Dephasing of G-band phonons in single-wall carbon nanotubes probed via impulsive stimulated Raman scattering

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2012
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American Physical Society
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We study the coherent dynamics of G-band phonons in single-wall carbon nanotubes through impulsive stimulated Stokes and anti-Stokes Raman scattering. The probe energy dependence of the phonon amplitude as well as the preferential occurrence between Stokes and anti-Stokes components in response to chirpedpulse excitation are well explained within our model. The temperature dependence of the observed dephasing rate clearly exhibits a thermally activated component, with an activation energy that coincides with the frequency of the radial breathing mode (RBM). This fact provides a clear picture for the dephasing of G-band phonons by random frequency modulation via interaction with the RBM through anharmonicity.

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Kim, J.-H., Yee, K.-J., Lim, Y.-S., et al.. "Dephasing of G-band phonons in single-wall carbon nanotubes probed via impulsive stimulated Raman scattering." Physical Review B, 86, (2012) American Physical Society: 161415(R). http://dx.doi.org/10.1103/PhysRevB.86.161415.

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