3D Covalent Organic Frameworks with Interpenetrated pcb Topology Based on 8-Connected Cubic Nodes

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dc.citation.firstpage5728en_US
dc.citation.issueNumber13en_US
dc.citation.journalTitleJournal of the American Chemical Societyen_US
dc.citation.lastpage5733en_US
dc.citation.volumeNumber144en_US
dc.contributor.authorShan, Zhenen_US
dc.contributor.authorWu, Miaomiaoen_US
dc.contributor.authorZhu, Dongyangen_US
dc.contributor.authorWu, Xiaoweien_US
dc.contributor.authorZhang, Kanen_US
dc.contributor.authorVerduzco, Rafaelen_US
dc.contributor.authorZhang, Genen_US
dc.date.accessioned2022-05-25T14:49:59Zen_US
dc.date.available2022-05-25T14:49:59Zen_US
dc.date.issued2022en_US
dc.description.abstractThe connectivity of building units for 3D covalent organic frameworks (COFs) has long been primarily 4 and 6, which have severely curtailed the structural diversity of 3D COFs. Here we demonstrate the successful design and synthesis of a porphyrin based, 8-connected building block with cubic configuration, which could be further reticulated into an unprecedented interpenetrated pcb topology by imine condensation with linear amine monomers. This study presents the first case of high-connectivity building units bearing 8-connected cubic nodes, thus greatly enriching the topological possibilities of 3D COFs.en_US
dc.identifier.citationShan, Zhen, Wu, Miaomiao, Zhu, Dongyang, et al.. "3D Covalent Organic Frameworks with Interpenetrated pcb Topology Based on 8-Connected Cubic Nodes." <i>Journal of the American Chemical Society,</i> 144, no. 13 (2022) American Chemical Society: 5728-5733. https://doi.org/10.1021/jacs.2c01037.en_US
dc.identifier.doihttps://doi.org/10.1021/jacs.2c01037en_US
dc.identifier.urihttps://hdl.handle.net/1911/112400en_US
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsThis is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by the American Chemical Society.en_US
dc.title3D Covalent Organic Frameworks with Interpenetrated pcb Topology Based on 8-Connected Cubic Nodesen_US
dc.typeJournal articleen_US
dc.type.dcmiTexten_US
dc.type.publicationpost-printen_US
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