Magnetic Diagram of the High-Pressure Stabilized Multiferroic Perovskites of the BiFe1-yScyO3 Series

Simple item page
dc.citation.articleNumber950en_US
dc.citation.issueNumber10en_US
dc.citation.journalTitleCrystalsen_US
dc.citation.volumeNumber10en_US
dc.contributor.authorFertman, Elena L.en_US
dc.contributor.authorFedorchenko, Alexey V.en_US
dc.contributor.authorČižmár, Eriken_US
dc.contributor.authorVorobiov, Serhiien_US
dc.contributor.authorFeher, Alexanderen_US
dc.contributor.authorRadyush, Yury V.en_US
dc.contributor.authorPushkarev, Anatoli V.en_US
dc.contributor.authorOlekhnovich, Nikolai M.en_US
dc.contributor.authorStanulis, Andriusen_US
dc.contributor.authorBarron, Andrew R.en_US
dc.contributor.authorKhalyavin, Dmitry D.en_US
dc.contributor.authorSalak, Andrei N.en_US
dc.date.accessioned2020-11-06T02:02:48Zen_US
dc.date.available2020-11-06T02:02:48Zen_US
dc.date.issued2020en_US
dc.description.abstractMagnetic properties of the high-pressure stabilized perovskite BiFe1-yScyO3 phases (0.1 ≤ y ≤ 0.9) have been studied by means of magnetization measurements and neutron diffraction. The metastable perovskites of this series undergo irreversible polymorphic transformations upon annealing, the phenomenon referred to as conversion polymorphism. It has been found that the solid solutions with y ≥ 0.70 exhibit no long-range magnetic ordering regardless of their polymorph modification, while those with y ≤ 0.60 are all antiferromagnets. Depending on the scandium content, temperature and structural distortions, three types of the antiferromagnetic orderings, involving collinear, canted and cycloidal spin arrangements, have been revealed in the phases obtained via conversion polymorphism and the corresponding magnetic phase diagram has been suggested.en_US
dc.identifier.citationFertman, Elena L., Fedorchenko, Alexey V., Čižmár, Erik, et al.. "Magnetic Diagram of the High-Pressure Stabilized Multiferroic Perovskites of the BiFe1-yScyO3 Series." <i>Crystals,</i> 10, no. 10 (2020) MDPI: https://doi.org/10.3390/cryst10100950.en_US
dc.identifier.doihttps://doi.org/10.3390/cryst10100950en_US
dc.identifier.urihttps://hdl.handle.net/1911/109517en_US
dc.language.isoengen_US
dc.publisherMDPIen_US
dc.rightsThis is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly citeden_US
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/en_US
dc.subject.keywordhigh-pressure synthesisen_US
dc.subject.keywordconversion polymorphismen_US
dc.subject.keywordoxygen octahedral tiltingen_US
dc.subject.keywordG-type antiferromagneticen_US
dc.subject.keywordweak ferromagnetismen_US
dc.subject.keywordcollinear magnetic ground stateen_US
dc.titleMagnetic Diagram of the High-Pressure Stabilized Multiferroic Perovskites of the BiFe1-yScyO3 Seriesen_US
dc.typeJournal articleen_US
dc.type.dcmiTexten_US
dc.type.publicationpublisher versionen_US
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
crystals-10-00950-v2.pdf
Size:
1001.88 KB
Format:
Adobe Portable Document Format
Description:
Download
Collections
Faculty Publications
Chemistry Publications
Materials Science and NanoEngineering Publications