Reduction Kinetics of the Nanocluster [HxPMo12O40⊂H4Mo72Fe30(O2CMe)15O254(H2O)98-y(EtOH)y]

Simple item page
dc.citation.firstpage325en_US
dc.citation.issueNumber2en_US
dc.citation.journalTitleJournal of Cluster Scienceen_US
dc.citation.lastpage335en_US
dc.citation.volumeNumber29en_US
dc.contributor.authorEsquenazi, Gibran L.en_US
dc.contributor.authorBarron, Andrew R.en_US
dc.date.accessioned2018-07-11T15:59:27Zen_US
dc.date.available2018-07-11T15:59:27Zen_US
dc.date.issued2018en_US
dc.description.abstractThe reduction of the molecular iron-molybdenum-nanocluster, [HxPMo12O40⊂H4Mo72Fe30(O2CMe)15O254(H2O)98-y(EtOH)y](FeMoC), was studied using model free isoconversional methods. The reduction kinetics were evaluated using the non-isothermal thermogravimetric measurements at four different heating rates from 5 to 20 °C/min in a 5% hydrogen atmosphere (argon balance). The apparent activation energy dependence on conversion derived from the isoconversional Kissinger–Akahira–Sunose (KAS) and Vyazovkin methods reveals a complex multi-step process with values ranging from 60.8 ± 13.3 to 183 ± 6.3 kJ/mol. The kinetic results were validated by isothermal predictions. The results herein are useful for optimization and development of FeMoC derived Fe–Mo nanoalloy systems.en_US
dc.identifier.citationEsquenazi, Gibran L. and Barron, Andrew R.. "Reduction Kinetics of the Nanocluster [HxPMo12O40⊂H4Mo72Fe30(O2CMe)15O254(H2O)98-y(EtOH)y]." <i>Journal of Cluster Science,</i> 29, no. 2 (2018) Springer: 325-335. https://doi.org/10.1007/s10876-018-1335-0.en_US
dc.identifier.doihttps://doi.org/10.1007/s10876-018-1335-0en_US
dc.identifier.urihttps://hdl.handle.net/1911/102368en_US
dc.language.isoengen_US
dc.publisherSpringeren_US
dc.rightsThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.en_US
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/en_US
dc.subject.keywordreduction kineticsen_US
dc.subject.keywordisoconversional model free methoden_US
dc.subject.keywordironen_US
dc.subject.keywordmolybdenumen_US
dc.subject.keywordnanoclusteren_US
dc.titleReduction Kinetics of the Nanocluster [HxPMo12O40⊂H4Mo72Fe30(O2CMe)15O254(H2O)98-y(EtOH)y]en_US
dc.typeJournal articleen_US
dc.type.dcmiTexten_US
dc.type.publicationpublisher versionen_US
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
ReductionKineticsNanocluster.pdf
Size:
1.28 MB
Format:
Adobe Portable Document Format
Description:
Download
Collections
Faculty Publications
Chemistry Publications
Materials Science and NanoEngineering Publications