Non-Deprotonative Primary and Secondary Amination of (Hetero)Arylmetals

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dc.citation.firstpage115en_US
dc.citation.issueNumber1en_US
dc.citation.journalTitleJournal of the American Chemical Societyen_US
dc.citation.lastpage118en_US
dc.citation.volumeNumber139en_US
dc.contributor.authorZhou, Zheen_US
dc.contributor.authorMa, Zhiweien_US
dc.contributor.authorBehnke, Nicole Erinen_US
dc.contributor.authorGao, Hongyinen_US
dc.contributor.authorKürti, Lászlóen_US
dc.contributor.orgBioScience Research Collaborativeen_US
dc.date.accessioned2017-01-27T19:05:16Zen_US
dc.date.available2017-01-27T19:05:16Zen_US
dc.date.issued2017en_US
dc.description.abstractHerein we disclose a novel method for the facile transfer of primary (−NH2) and secondary amino groups (−NHR) to heteroaryl- as well as arylcuprates at low temperature without the need for precious metal catalysts, ligands, excess reagents, protecting and/or directing groups. This one-pot transformation allows unprecedented functional group tolerance and it is well-suited for the amination of electron-rich, electron-deficient as well as structurally complex (hetero)arylmetals. In some of the cases, only catalytic amounts of a copper(I) salt is required.en_US
dc.identifier.citationZhou, Zhe, Ma, Zhiwei, Behnke, Nicole Erin, et al.. "Non-Deprotonative Primary and Secondary Amination of (Hetero)Arylmetals." <i>Journal of the American Chemical Society,</i> 139, no. 1 (2017) American Chemical Society: 115-118. http://dx.doi.org/10.1021/jacs.6b12712.en_US
dc.identifier.doihttp://dx.doi.org/10.1021/jacs.6b12712en_US
dc.identifier.urihttps://hdl.handle.net/1911/93785en_US
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsThis is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by the American Chemical Society.en_US
dc.titleNon-Deprotonative Primary and Secondary Amination of (Hetero)Arylmetalsen_US
dc.typeJournal articleen_US
dc.type.dcmiTexten_US
dc.type.publicationpost-printen_US
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