Direct and Stereospecific Synthesis of N-H and N-Alkyl Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acids

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dc.citation.firstpage10018
dc.citation.issueNumber33
dc.citation.journalTitleAngewandte Chemie
dc.citation.lastpage10022
dc.citation.volumeNumber129
dc.contributor.authorMa, Zhiwei
dc.contributor.authorZhou, Zhe
dc.contributor.authorKürti, László
dc.date.accessioned2017-11-14T18:08:23Z
dc.date.available2017-11-14T18:08:23Z
dc.date.issued2017
dc.description.abstractA RhII-catalyzed direct and stereospecific N-H- and N-alkyl aziridination of olefins is reported that uses hydroxylamine-O-sulfonic acids as inexpensive, readily available, and nitro group-free aminating reagents. Unactivated olefins, featuring a wide range of functional groups, are converted into the corresponding N-H or N-alkyl aziridines in good to excellent yields. This operationally simple, scalable transformation proceeds efficiently at ambient temperature and is tolerant towards oxygen and trace moisture.
dc.identifier.citationMa, Zhiwei, Zhou, Zhe and Kürti, László. "Direct and Stereospecific Synthesis of N-H and N-Alkyl Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acids." <i>Angewandte Chemie,</i> 129, no. 33 (2017) Wiley: 10018-10022. https://doi.org/10.1002/ange.201705530.
dc.identifier.digitalFINAL_Angewandte_HOSA_May_30_2017_Zhiwei_ZZ_Kurti-1
dc.identifier.doihttps://doi.org/10.1002/ange.201705530
dc.identifier.urihttps://hdl.handle.net/1911/98799
dc.language.isoeng
dc.publisherWiley
dc.rightsThis is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by Wiley.
dc.subject.keywordaziridination
dc.subject.keyworddirhodium catalysis
dc.subject.keywordhydroxylamine-O-sulfonic acid
dc.subject.keywordnitrenoids
dc.subject.keywordolefins
dc.titleDirect and Stereospecific Synthesis of N-H and N-Alkyl Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acids
dc.typeJournal article
dc.type.dcmiText
dc.type.publicationpost-print
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