Direct and Stereospecific Synthesis of N-H and N-Alkyl Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acids
| dc.citation.firstpage | 10018 | en_US |
| dc.citation.issueNumber | 33 | en_US |
| dc.citation.journalTitle | Angewandte Chemie | en_US |
| dc.citation.lastpage | 10022 | en_US |
| dc.citation.volumeNumber | 129 | en_US |
| dc.contributor.author | Ma, Zhiwei | en_US |
| dc.contributor.author | Zhou, Zhe | en_US |
| dc.contributor.author | Kürti, László | en_US |
| dc.date.accessioned | 2017-11-14T18:08:23Z | en_US |
| dc.date.available | 2017-11-14T18:08:23Z | en_US |
| dc.date.issued | 2017 | en_US |
| dc.description.abstract | A RhII-catalyzed direct and stereospecific N-H- and N-alkyl aziridination of olefins is reported that uses hydroxylamine-O-sulfonic acids as inexpensive, readily available, and nitro group-free aminating reagents. Unactivated olefins, featuring a wide range of functional groups, are converted into the corresponding N-H or N-alkyl aziridines in good to excellent yields. This operationally simple, scalable transformation proceeds efficiently at ambient temperature and is tolerant towards oxygen and trace moisture. | en_US |
| dc.identifier.citation | Ma, Zhiwei, Zhou, Zhe and Kürti, László. "Direct and Stereospecific Synthesis of N-H and N-Alkyl Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acids." <i>Angewandte Chemie,</i> 129, no. 33 (2017) Wiley: 10018-10022. https://doi.org/10.1002/ange.201705530. | en_US |
| dc.identifier.digital | FINAL_Angewandte_HOSA_May_30_2017_Zhiwei_ZZ_Kurti-1 | en_US |
| dc.identifier.doi | https://doi.org/10.1002/ange.201705530 | en_US |
| dc.identifier.uri | https://hdl.handle.net/1911/98799 | en_US |
| dc.language.iso | eng | en_US |
| dc.publisher | Wiley | en_US |
| dc.rights | This is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by Wiley. | en_US |
| dc.subject.keyword | aziridination | en_US |
| dc.subject.keyword | dirhodium catalysis | en_US |
| dc.subject.keyword | hydroxylamine-O-sulfonic acid | en_US |
| dc.subject.keyword | nitrenoids | en_US |
| dc.subject.keyword | olefins | en_US |
| dc.title | Direct and Stereospecific Synthesis of N-H and N-Alkyl Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acids | en_US |
| dc.type | Journal article | en_US |
| dc.type.dcmi | Text | en_US |
| dc.type.publication | post-print | en_US |
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