Exploring the Photophysical Properties of UiO-67 MOF Doped with Rhenium Carbonyl Complexes

Simple item page
dc.citation.articleNumber100127en_US
dc.citation.journalTitleJournal of Photochemistry and Photobiologyen_US
dc.citation.volumeNumber11en_US
dc.contributor.authorLing, Kexinen_US
dc.contributor.authorOgle, Meredith M.en_US
dc.contributor.authorFlores, Ericken_US
dc.contributor.authorGodoy, Fernandoen_US
dc.contributor.authorMartí, Angel A.en_US
dc.date.accessioned2022-08-04T14:53:11Zen_US
dc.date.available2022-08-04T14:53:11Zen_US
dc.date.issued2022en_US
dc.description.abstractDirectly coordinating transition metal catalysts to the linkers of stable metal organic frameworks (MOFs) is a sleek solution to increasing the longevity of the catalyst. Photoluminescence metal complexes incorporated in MOFs have risen in interest lately. Particularly, Re(bpydc)(CO)3Cl (bpydc = 2,2’-bipyridine-5,5’-dicarboxylic acid) doped zirconium-based MOFs (Re-UiO-67) and their use in the photocatalytic reduction of CO2 have attracted considerable attention. Nonetheless, the photophysical characteristics of Re-UiO-67 as a function of loading have not been well explored. Here we analyzed the structural and compositional properties of Re-UiO-67 and showed that the photoluminescence properties of rhenium doped MOFs, including emission intensity, maximum, and lifetime, can be tuned by changing the rhenium loading. The photoluminescence of the film made of Re-UiO-67 exposed to different vapors also exhibited vapoluminescence, luminescence vapochromism, and vapotemporism. Understanding of photophysical properties of the Re-doped MOFs material could provide guidance for further photocatalytic, solar energy conversion and sensing applications.en_US
dc.identifier.citationLing, Kexin, Ogle, Meredith M., Flores, Erick, et al.. "Exploring the Photophysical Properties of UiO-67 MOF Doped with Rhenium Carbonyl Complexes." <i>Journal of Photochemistry and Photobiology,</i> 11, (2022) Elsevier: https://doi.org/10.1016/j.jpap.2022.100127.en_US
dc.identifier.digital1-s2-0-S2666469022000203-mainen_US
dc.identifier.doihttps://doi.org/10.1016/j.jpap.2022.100127en_US
dc.identifier.urihttps://hdl.handle.net/1911/112943en_US
dc.language.isoengen_US
dc.publisherElsevieren_US
dc.rightsThis is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/bync-nd/4.0/).en_US
dc.rights.urihttp://creativecommons.org/licenses/bync-nd/4.0/).en_US
dc.titleExploring the Photophysical Properties of UiO-67 MOF Doped with Rhenium Carbonyl Complexesen_US
dc.typeJournal articleen_US
dc.type.dcmiTexten_US
dc.type.publicationpublisher versionen_US
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
1-s2-0-S2666469022000203-main.pdf
Size:
2 MB
Format:
Adobe Portable Document Format
Download
Collections
Faculty Publications
Bioengineering Publications
Chemistry Publications
Materials Science and NanoEngineering Publications