Exploring the Photophysical Properties of UiO-67 MOF Doped with Rhenium Carbonyl Complexes

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dc.citation.articleNumber100127
dc.citation.journalTitleJournal of Photochemistry and Photobiology
dc.citation.volumeNumber11
dc.contributor.authorLing, Kexin
dc.contributor.authorOgle, Meredith M.
dc.contributor.authorFlores, Erick
dc.contributor.authorGodoy, Fernando
dc.contributor.authorMartí, Angel A.
dc.date.accessioned2022-08-04T14:53:11Z
dc.date.available2022-08-04T14:53:11Z
dc.date.issued2022
dc.description.abstractDirectly coordinating transition metal catalysts to the linkers of stable metal organic frameworks (MOFs) is a sleek solution to increasing the longevity of the catalyst. Photoluminescence metal complexes incorporated in MOFs have risen in interest lately. Particularly, Re(bpydc)(CO)3Cl (bpydc = 2,2’-bipyridine-5,5’-dicarboxylic acid) doped zirconium-based MOFs (Re-UiO-67) and their use in the photocatalytic reduction of CO2 have attracted considerable attention. Nonetheless, the photophysical characteristics of Re-UiO-67 as a function of loading have not been well explored. Here we analyzed the structural and compositional properties of Re-UiO-67 and showed that the photoluminescence properties of rhenium doped MOFs, including emission intensity, maximum, and lifetime, can be tuned by changing the rhenium loading. The photoluminescence of the film made of Re-UiO-67 exposed to different vapors also exhibited vapoluminescence, luminescence vapochromism, and vapotemporism. Understanding of photophysical properties of the Re-doped MOFs material could provide guidance for further photocatalytic, solar energy conversion and sensing applications.
dc.identifier.citationLing, Kexin, Ogle, Meredith M., Flores, Erick, et al.. "Exploring the Photophysical Properties of UiO-67 MOF Doped with Rhenium Carbonyl Complexes." <i>Journal of Photochemistry and Photobiology,</i> 11, (2022) Elsevier: https://doi.org/10.1016/j.jpap.2022.100127.
dc.identifier.digital1-s2-0-S2666469022000203-main
dc.identifier.doihttps://doi.org/10.1016/j.jpap.2022.100127
dc.identifier.urihttps://hdl.handle.net/1911/112943
dc.language.isoeng
dc.publisherElsevier
dc.rightsThis is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/bync-nd/4.0/).
dc.rights.urihttp://creativecommons.org/licenses/bync-nd/4.0/).
dc.titleExploring the Photophysical Properties of UiO-67 MOF Doped with Rhenium Carbonyl Complexes
dc.typeJournal article
dc.type.dcmiText
dc.type.publicationpublisher version
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