Interaction of Surface-Modified Alumina Nanoparticles and Surfactants at an Oil/Water Interface: A Neutron Reflectometry, Scattering, and Enhanced Oil Recovery Study
dc.citation.firstpage | 19505 | |
dc.citation.issueNumber | 17 | |
dc.citation.journalTitle | ACS Applied Materials & Interfaces | |
dc.citation.lastpage | 19514 | |
dc.citation.volumeNumber | 14 | |
dc.contributor.author | Al-Shatty, Wafaa | |
dc.contributor.author | Campana, Mario | |
dc.contributor.author | Alexander, Shirin | |
dc.contributor.author | Barron, Andrew R. | |
dc.date.accessioned | 2022-05-25T17:37:44Z | |
dc.date.available | 2022-05-25T17:37:44Z | |
dc.date.issued | 2022 | |
dc.description.abstract | The evaluation of the mechanism of nanoparticle (NP)/surfactant complex adsorption at the critical oil/water interface was studied. A sophisticated technique (neutron reflectometry) was used to give a unique insight on NP/oil interactions in oil recovery systems. Herein, the adsorption of two modified alumina NPs with different degrees of hydrophobicity [hydrophilic = 2-[2-(2-methoxyethoxy)ethoxy]acetic acid and hydrophobic = octanoic acid (OCT)] stabilized with two different surfactants were studied at the oil/water interface. A thin layer of deuterated (D) and hydrogenated (H) hexadecane (contrast matching silicon substrate) oil was formed on a silicon block by a spin coating freeze process. The distribution of the NPs across the oil/water interface with the CTAB surfactant is similar between the two systems. NPs coated with CTAB have more affinity toward the oil/water interface, which explains the oil recovery increase by around 5% when flooding the core with the OCT-NP/CTAB system compared to the surfactant flooding alone. These results suggest that the NP/surfactant complexes can have potential usage in EOR recovery applications. | |
dc.identifier.citation | Al-Shatty, Wafaa, Campana, Mario, Alexander, Shirin, et al.. "Interaction of Surface-Modified Alumina Nanoparticles and Surfactants at an Oil/Water Interface: A Neutron Reflectometry, Scattering, and Enhanced Oil Recovery Study." <i>ACS Applied Materials & Interfaces,</i> 14, no. 17 (2022) American Chemical Society: 19505-19514. https://doi.org/10.1021/acsami.2c02228. | |
dc.identifier.digital | acsami-2c02228 | |
dc.identifier.doi | https://doi.org/10.1021/acsami.2c02228 | |
dc.identifier.uri | https://hdl.handle.net/1911/112417 | |
dc.language.iso | eng | |
dc.publisher | American Chemical Society | |
dc.rights | This article is distributed under the terms of the Creative Commons Attribution License (CC-BY 4.0) | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.title | Interaction of Surface-Modified Alumina Nanoparticles and Surfactants at an Oil/Water Interface: A Neutron Reflectometry, Scattering, and Enhanced Oil Recovery Study | |
dc.type | Journal article | |
dc.type.dcmi | Text | |
dc.type.publication | publisher version |
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