Quantum networks represent one of the most promising technologies for the future development of quantum information science (QIS), with broad applications that range from secure communication and distributed quantum computing to enhanced sensing. Solid-state platforms are ideal candidates for the implementation of such quantum networks, since they offer easy accessibility to device integration and spin-photon interfaces capable of processing and storing qubits, as well as connecting remote network nodes by sending photons through optical fibers. In this thesis, we focus on single T centers, which are a novel type of color centers in silicon. This quantum defect stands out as a promising candidate for quantum networking applications due to its telecom optical transition, superior spin performance, and its compatibility with the technologically mature silicon platform. Here, we present our initial studies on single T centers, including the design and fabrication of nanophotonic devices in a silicon-on-insulator (SOI) sample with integrated T centers, and the cavity-enhanced fluorescence emission of single T centers, which have achieved the highest Purcell factor (Pt = 43) to date. Moreover, our experimental and numerical results allow us to determine a lower bound to the T center quantum efficiency of η = 23.4%, which is a key optical parameter for T centers that is largely overlooked in the community. Additionally, we present preliminary bulk spectroscopy work on ensemble T centers. The same setup will be exploited towards the exploration of novel quantum defects in silicon, including the boron-carbon (B-C) complex defect and the Ti+ defect, which are expected to have similar or better optical properties than the T center.