Understanding the effect of carbon nanotube functionalization on copper electrodeposition

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dc.citation.firstpage731en_US
dc.citation.issueNumber8en_US
dc.citation.journalTitleJournal of Applied Electrochemistryen_US
dc.citation.lastpage741en_US
dc.citation.volumeNumber49en_US
dc.contributor.authorKazimierska, Ewaen_US
dc.contributor.authorAndreoli, Enricoen_US
dc.contributor.authorBarron, Andrew R.en_US
dc.date.accessioned2019-11-22T16:19:51Zen_US
dc.date.available2019-11-22T16:19:51Zen_US
dc.date.issued2019en_US
dc.description.abstractThe dynamics of electrochemical deposition and dissolution of copper in the presence of functionalized multiwalled carbon nanotubes in solution has been studied in detail using an electrochemical quartz crystal microbalance. Results demonstrate the central role of carbon nanotube functionalization on the values of mass and current densities of copper deposition. Amine functionalization increases competitive hydrogen evolution without significantly affecting the total amount of deposited copper, whereas carboxylic functionalization clearly enhances the deposition of larger amounts of smoother copper deposits. Molar mass analysis of deposited species reveals interactions of carbon nanotubes with the electrode surface dependent on the type of functionalization. The effect of carbon nanotube functionalization should be closely considered in the development of electrochemical strategies for the integration of carbon nanotubes in metallic copper.en_US
dc.identifier.citationKazimierska, Ewa, Andreoli, Enrico and Barron, Andrew R.. "Understanding the effect of carbon nanotube functionalization on copper electrodeposition." <i>Journal of Applied Electrochemistry,</i> 49, no. 8 (2019) Springer: 731-741. https://doi.org/10.1007/s10800-019-01318-x.en_US
dc.identifier.digitalKazimierska2019en_US
dc.identifier.doihttps://doi.org/10.1007/s10800-019-01318-xen_US
dc.identifier.urihttps://hdl.handle.net/1911/107709en_US
dc.language.isoengen_US
dc.publisherSpringeren_US
dc.rightsThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.en_US
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/),en_US
dc.subject.keywordCopperen_US
dc.subject.keywordCarbon nanotubesen_US
dc.subject.keywordCompositeen_US
dc.subject.keywordFunctionalizationen_US
dc.subject.keywordElectrodepositionen_US
dc.titleUnderstanding the effect of carbon nanotube functionalization on copper electrodepositionen_US
dc.typeJournal articleen_US
dc.type.dcmiTexten_US
dc.type.publicationpublisher versionen_US
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