Understanding the effect of carbon nanotube functionalization on copper electrodeposition

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dc.citation.firstpage731
dc.citation.issueNumber8
dc.citation.journalTitleJournal of Applied Electrochemistry
dc.citation.lastpage741
dc.citation.volumeNumber49
dc.contributor.authorKazimierska, Ewa
dc.contributor.authorAndreoli, Enrico
dc.contributor.authorBarron, Andrew R.
dc.date.accessioned2019-11-22T16:19:51Z
dc.date.available2019-11-22T16:19:51Z
dc.date.issued2019
dc.description.abstractThe dynamics of electrochemical deposition and dissolution of copper in the presence of functionalized multiwalled carbon nanotubes in solution has been studied in detail using an electrochemical quartz crystal microbalance. Results demonstrate the central role of carbon nanotube functionalization on the values of mass and current densities of copper deposition. Amine functionalization increases competitive hydrogen evolution without significantly affecting the total amount of deposited copper, whereas carboxylic functionalization clearly enhances the deposition of larger amounts of smoother copper deposits. Molar mass analysis of deposited species reveals interactions of carbon nanotubes with the electrode surface dependent on the type of functionalization. The effect of carbon nanotube functionalization should be closely considered in the development of electrochemical strategies for the integration of carbon nanotubes in metallic copper.
dc.identifier.citationKazimierska, Ewa, Andreoli, Enrico and Barron, Andrew R.. "Understanding the effect of carbon nanotube functionalization on copper electrodeposition." <i>Journal of Applied Electrochemistry,</i> 49, no. 8 (2019) Springer: 731-741. https://doi.org/10.1007/s10800-019-01318-x.
dc.identifier.digitalKazimierska2019
dc.identifier.doihttps://doi.org/10.1007/s10800-019-01318-x
dc.identifier.urihttps://hdl.handle.net/1911/107709
dc.language.isoeng
dc.publisherSpringer
dc.rightsThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/),
dc.subject.keywordCopper
dc.subject.keywordCarbon nanotubes
dc.subject.keywordComposite
dc.subject.keywordFunctionalization
dc.subject.keywordElectrodeposition
dc.titleUnderstanding the effect of carbon nanotube functionalization on copper electrodeposition
dc.typeJournal article
dc.type.dcmiText
dc.type.publicationpublisher version
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