The Unexpected Isolation of Bismuth Tris(carboxylate) Hydrates: Syntheses and Structures of [Bi(Hsal)3(H2O)] and [Bi(Hanth)3(H2O)] (H2sal = 2-OH-C6H4CO2H, Hanth = 2-NH2-C6H4CO2H)
| dc.citation.firstpage | 605 | |
| dc.citation.issueNumber | 4 | |
| dc.citation.journalTitle | European Journal of Inorganic Chemistry | |
| dc.citation.lastpage | 608 | |
| dc.citation.volumeNumber | 2015 | |
| dc.contributor.author | Kumar, Ish | |
| dc.contributor.author | Andrews, Phil | |
| dc.contributor.author | Whitmire, Kenton H. | |
| dc.date.accessioned | 2015-02-11T15:45:10Z | |
| dc.date.available | 2015-02-11T15:45:10Z | |
| dc.date.issued | 2015 | |
| dc.description.abstract | A complex of the composition [Bi(2-OH-C6H4CO2)3(H2O)] (1) was isolated from the 1:3 reaction of BiPh3 with H2sal (H2sal = salicylic acid = 2-OH-C6H4CO2H) in wet xylene, and the analogous anthranilate compound [Bi(2-NH2-C6H4CO2)3(H2O)] (2) was obtained from the 1:3 reaction of Bi(OtBu)3 with Hanth (Hanth = anthranilic acid = 2-NH2-C6H4CO2H) in tetrahydrofuran. Compounds 1 and 2 were fully characterized spectroscopically and by single-crystal X-ray diffraction. Compounds 1 and 2 crystallize in the triclinic space group and display the η2-(O,O′) binding mode for the oxygen atoms of the carboxylate ligands. There are two independent molecules in the asymmetric units of 1 and 2 that are connected by a weak bridging interaction of the OH or NH2 group to an adjacent molecule. Both bismuth atoms are bound to a H2O molecule, but the distances are highly asymmetric, long Bi···O lengths ranging from 2.74 to 2.89 Å. | |
| dc.identifier.citation | Kumar, Ish, Andrews, Phil and Whitmire, Kenton H.. "The Unexpected Isolation of Bismuth Tris(carboxylate) Hydrates: Syntheses and Structures of [Bi(Hsal)3(H2O)] and [Bi(Hanth)3(H2O)] (H2sal = 2-OH-C6H4CO2H, Hanth = 2-NH2-C6H4CO2H)." <i>European Journal of Inorganic Chemistry,</i> 2015, no. 4 (2015) Wiley: 605-608. http://dx.doi.org/10.1002/ejic.201403019. | |
| dc.identifier.doi | http://dx.doi.org/10.1002/ejic.201403019 | |
| dc.identifier.uri | https://hdl.handle.net/1911/79027 | |
| dc.language.iso | eng | |
| dc.publisher | Wiley | |
| dc.rights | This is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by Wiley. | |
| dc.subject.keyword | bismuth | |
| dc.subject.keyword | salicylates | |
| dc.subject.keyword | carb-oxylates | |
| dc.subject.keyword | hydrates | |
| dc.subject.keyword | hydrolysis | |
| dc.title | The Unexpected Isolation of Bismuth Tris(carboxylate) Hydrates: Syntheses and Structures of [Bi(Hsal)3(H2O)] and [Bi(Hanth)3(H2O)] (H2sal = 2-OH-C6H4CO2H, Hanth = 2-NH2-C6H4CO2H) | |
| dc.type | Journal article | |
| dc.type.dcmi | Text | |
| dc.type.publication | post-print |
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