Reversible dioxygen uptake at [Cu4] clusters

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dc.citation.firstpage5327
dc.citation.issueNumber14
dc.citation.journalTitleChemical Science
dc.citation.lastpage5332
dc.citation.volumeNumber15
dc.contributor.authorOsei, Manasseh Kusi
dc.contributor.authorMirzaei, Saber
dc.contributor.authorMirzaei, M. Saeed
dc.contributor.authorValles, Agustin
dc.contributor.authorSánchez, Raúl Hernández
dc.date.accessioned2024-07-25T20:55:16Z
dc.date.available2024-07-25T20:55:16Z
dc.date.issued2024
dc.description.abstractDioxygen binding solely through non-covalent interactions is rare. In living systems, dioxygen transport takes place via iron or copper-containing biological cofactors. Specifically, a reversible covalent interaction is established when O2 binds to the mono or polynuclear metal center. However, O2 stabilization in the absence of covalent bond formation is challenging and rarely observed. Here, we demonstrate a unique example of reversible non-covalent binding of dioxygen within the cavity of a well-defined synthetic all-Cu(I) tetracopper cluster.
dc.identifier.citationKusi Osei, M., Mirzaei, S., Saeed Mirzaei, M., Valles, A., & Sánchez, R. H. (2024). Reversible dioxygen uptake at [Cu 4 ] clusters. Chemical Science, 15(14), 5327–5332. https://doi.org/10.1039/D3SC06390A
dc.identifier.digitald3sc06390a
dc.identifier.doihttps://doi.org/10.1039/D3SC06390A
dc.identifier.urihttps://hdl.handle.net/1911/117509
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.rightsExcept where otherwise noted, this work is licensed under a Creative Commons Attribution (CC BY) license.  Permission to reuse, publish, or reproduce the work beyond the terms of the license or beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder.
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/
dc.titleReversible dioxygen uptake at [Cu4] clusters
dc.typeJournal article
dc.type.dcmiText
dc.type.publicationpublisher version
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