Anionic Bismuth-Oxido Carboxylate Clusters with Transition Metal Countercations

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dc.citation.firstpage11560en_US
dc.citation.issueNumber21en_US
dc.citation.journalTitleInorganic Chemistryen_US
dc.citation.lastpage11569en_US
dc.citation.volumeNumber55en_US
dc.contributor.authorFernandez, Ismael I. Loeraen_US
dc.contributor.authorDonaldson, Samantha L.en_US
dc.contributor.authorSchipper, Desmond E.en_US
dc.contributor.authorAndleeb, Sohailaen_US
dc.contributor.authorWhitmire, Kenton H.en_US
dc.date.accessioned2017-01-27T19:05:16Zen_US
dc.date.available2017-01-27T19:05:16Zen_US
dc.date.issued2016en_US
dc.description.abstractSix new anionic bismuth-oxido clusters containing trifluoroacetate ligands were prepared. These include two new Bi6O8 clusters: [M(NCMe)2(H2O)4]3[Bi6(μ3-O)4(μ3-OH)4(CF3CO2)12] with an octahedral Bi6O4(OH)4 core (M = Ni, 1a; Co, 1b) and four Bi4O2 clusters, {[Co(NCMe)6][Bi4(μ3-O)2(CF3CO2)10]}n (2a), {[Co{HC(MeCO)2(MeCNH)}2][Bi4(μ3-O)2(CF3CO2)10]·2[CF3CO2]·2[CF3CO2H]·2[H2O]}n (2b), {[Cu(NCMe)4]2[Bi4(μ3-O)2(CF3CO2)10]·2[CF3CO2H]}n (2c), and {[Me4N]2[Bi4(μ3-O)2(CF3CO2)10]·2[CF3CO2H]}n (2d). These are among the first bismuth-oxido anionic clusters synthesized, and the first to have transition metal countercations. The Bi6O8 anion in 1a and 1b is a high-symmetry octahedron. Additionally, two of the new Bi4O2 clusters are arranged in 1D polymeric structures via bridging carboxylate ligands. The cation in compound 2c had not been previously characterized and was also observed in the synthesis of [Co{HC(MeCO)2(MeCNH)}2][Bi(NO3)6] (3). The new compounds were characterized using single crystal X-ray crystallography and elemental analysis.en_US
dc.identifier.citationFernandez, Ismael I. Loera, Donaldson, Samantha L., Schipper, Desmond E., et al.. "Anionic Bismuth-Oxido Carboxylate Clusters with Transition Metal Countercations." <i>Inorganic Chemistry,</i> 55, no. 21 (2016) American Chemical Society: 11560-11569. http://dx.doi.org/10.1021/acs.inorgchem.6b02092.en_US
dc.identifier.doihttp://dx.doi.org/10.1021/acs.inorgchem.6b02092en_US
dc.identifier.urihttps://hdl.handle.net/1911/93790en_US
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsThis is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by the American Chemical Society.en_US
dc.titleAnionic Bismuth-Oxido Carboxylate Clusters with Transition Metal Countercationsen_US
dc.typeJournal articleen_US
dc.type.dcmiTexten_US
dc.type.publicationpost-printen_US
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