Iron carbonyl clusters with ECl2 units (E = P, As)
| dc.citation.firstpage | 279 | |
| dc.citation.journalTitle | Journal of Organometallic Chemistry | |
| dc.citation.lastpage | 285 | |
| dc.citation.volumeNumber | 849-850 | |
| dc.contributor.author | Schipper, Desmond E. | |
| dc.contributor.author | Chen, Jing-Han | |
| dc.contributor.author | Whitmire, Kenton H. | |
| dc.date.accessioned | 2017-11-14T18:08:22Z | |
| dc.date.available | 2017-11-14T18:08:22Z | |
| dc.date.issued | 2017 | |
| dc.description.abstract | Reaction of [PPN][HFe(CO)4] (PPN = bis(triphenylphosphine)iminium) with PCl3 in a 1:1 ratio produced small amounts of [PPN][P{Fe(CO)4}2Cl2] ([PPN][Ia]). Reaction of [Et4N][HFe(CO)4] with AsCl3 in a 1:0.75 ratio in THF at −78 °C produced [Et4N][As{Fe(CO)4}2Cl2] ([PPN][Ib]) as the majority product. The compound [PPN][(CO)4FePCl2O] ([PPN][II]) was obtained from the reaction of Fe2(CO)9 with PCl3 in THF. In contrast, [Et4N][HFe(CO)4] reacted with PCl3 at −78 °C in a 2:1 ratio to yield [Et4N][Fe2(CO)6{(μ4-PFe(CO)4)2(μ-CO)}{μ-PCl2}] ([Et4N][III]) as the majority product. The compounds were characterized spectroscopically and by single-crystal X-ray diffraction analyses. | |
| dc.identifier.citation | Schipper, Desmond E., Chen, Jing-Han and Whitmire, Kenton H.. "Iron carbonyl clusters with ECl2 units (E = P, As)." <i>Journal of Organometallic Chemistry,</i> 849-850, (2017) Elsevier: 279-285. https://doi.org/10.1016/j.jorganchem.2017.03.008. | |
| dc.identifier.digital | ECl2Manuscript2017.02.23_DES | |
| dc.identifier.doi | https://doi.org/10.1016/j.jorganchem.2017.03.008 | |
| dc.identifier.uri | https://hdl.handle.net/1911/98797 | |
| dc.language.iso | eng | |
| dc.publisher | Elsevier | |
| dc.rights | This is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by Elsevier. | |
| dc.subject.keyword | Phosphorus | |
| dc.subject.keyword | Arsenic | |
| dc.subject.keyword | Iron | |
| dc.subject.keyword | Metal carbonyl | |
| dc.subject.keyword | Pnictide | |
| dc.subject.keyword | Pnictogen | |
| dc.subject.keyword | Carbonyl cluster | |
| dc.subject.keyword | Chlorophosphine | |
| dc.subject.keyword | Phosphorus trichloride | |
| dc.title | Iron carbonyl clusters with ECl2 units (E = P, As) | |
| dc.type | Journal article | |
| dc.type.dcmi | Text | |
| dc.type.publication | post-print |