Breaking of Symmetry in Graphene Growth on Metal Substrates

dc.citation.firstpage115502en_US
dc.citation.issueNumber11en_US
dc.citation.journalTitlePhysical Review Lettersen_US
dc.citation.volumeNumber114en_US
dc.contributor.authorArtyukhov, Vasilii I.en_US
dc.contributor.authorHao, Yufengen_US
dc.contributor.authorRuoff, Rodney S.en_US
dc.contributor.authorYakobson, Boris I.en_US
dc.date.accessioned2016-06-10T19:01:57Z
dc.date.available2016-06-10T19:01:57Z
dc.date.issued2015en_US
dc.description.abstractIn graphene growth, island symmetry can become lower than the intrinsic symmetries of both graphene and the substrate. First-principles calculations and Monte Carlo modeling explain the shapes observed in our experiments and earlier studies for various metal surface symmetries. For equilibrium shape, edge energy variations δE manifest in distorted hexagons with different ground-state edge structures. In growth or nucleation, energy variation enters exponentially as ∼eδE/kBT, strongly amplifying the symmetry breaking, up to completely changing the shapes to triangular, ribbonlike, or rhombic.en_US
dc.identifier.citationArtyukhov, Vasilii I., Hao, Yufeng, Ruoff, Rodney S., et al.. "Breaking of Symmetry in Graphene Growth on Metal Substrates." <i>Physical Review Letters,</i> 114, no. 11 (2015) American Physical Society: 115502. http://dx.doi.org/10.1103/PhysRevLett.114.115502.
dc.identifier.doihttp://dx.doi.org/10.1103/PhysRevLett.114.115502en_US
dc.identifier.urihttps://hdl.handle.net/1911/90491
dc.language.isoengen_US
dc.publisherAmerican Physical Society
dc.rightsArticle is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
dc.titleBreaking of Symmetry in Graphene Growth on Metal Substratesen_US
dc.typeJournal articleen_US
dc.type.dcmiTexten_US
dc.type.publicationpublisher versionen_US
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