Synthesis and structural studies of the simplest bismuth(III) oxo-salicylate complex: [Bi4(m3-O)2(HO-2-C6H4CO2)8]×2 Solv (Solv = MeCN or MeNO2)

dc.citation.firstpage3556en_US
dc.citation.journalTitleChemical Communicationsen_US
dc.citation.lastpage3559en_US
dc.citation.volumeNumber50en_US
dc.contributor.authorBoyd , Tyler D.en_US
dc.contributor.authorKumar, Ishen_US
dc.contributor.authorWagner, Eric E.en_US
dc.contributor.authorWhitmire, Kenton H.en_US
dc.date.accessioned2014-07-30T16:23:09Z
dc.date.available2014-07-30T16:23:09Z
dc.date.issued2014en_US
dc.description.abstractReaction of BiPh3 with salicylic acid (HO-2-C6H4CO2H, H2Sal) at room temperature in wet acetonitrile or nitromethane leads to the facile formation of an oxo cluster compound with formula [Bi4(m3-O)2(HSal)8] solvated by either MeCN and MeNO2 (1×2MeCN or 1×2MeNO2). This simple procedure affords a convenient, high yield (>80%) synthesis of a single bismuth oxo cluster. Both adducts exhibit a nearly planar Bi4(m3-O)2 core. The solvent ligands are situated in the same coordination sites in both but at long Bi---N and Bi---O distances. The ease of preparation as a pure compound makes this an ideal starting material for study of bismuth oxo-salicylate chemistry.en_US
dc.identifier.citationBoyd , Tyler D., Kumar, Ish, Wagner, Eric E., et al.. "Synthesis and structural studies of the simplest bismuth(III) oxo-salicylate complex: [Bi4(m3-O)2(HO-2-C6H4CO2)8]×2 Solv (Solv = MeCN or MeNO2)." <i>Chemical Communications,</i> 50, (2014) Royal Society of Chemistry: 3556-3559. http://dx.doi.org/10.1039/C4CC00056K.
dc.identifier.doihttp://dx.doi.org/10.1039/C4CC00056Ken_US
dc.identifier.urihttps://hdl.handle.net/1911/76290
dc.language.isoengen_US
dc.publisherRoyal Society of Chemistry
dc.rightsThis is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by the Royal Society of Chemistry.en_US
dc.titleSynthesis and structural studies of the simplest bismuth(III) oxo-salicylate complex: [Bi4(m3-O)2(HO-2-C6H4CO2)8]×2 Solv (Solv = MeCN or MeNO2)en_US
dc.typeJournal articleen_US
dc.type.dcmiTexten_US
dc.type.publicationpost-printen_US
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