Synthesis and structural studies of the simplest bismuth(III) oxo-salicylate complex: [Bi4(m3-O)2(HO-2-C6H4CO2)8]×2 Solv (Solv = MeCN or MeNO2)
| dc.citation.firstpage | 3556 | |
| dc.citation.journalTitle | Chemical Communications | |
| dc.citation.lastpage | 3559 | |
| dc.citation.volumeNumber | 50 | |
| dc.contributor.author | Boyd , Tyler D. | |
| dc.contributor.author | Kumar, Ish | |
| dc.contributor.author | Wagner, Eric E. | |
| dc.contributor.author | Whitmire, Kenton H. | |
| dc.date.accessioned | 2014-07-30T16:23:09Z | |
| dc.date.available | 2014-07-30T16:23:09Z | |
| dc.date.issued | 2014 | |
| dc.description.abstract | Reaction of BiPh3 with salicylic acid (HO-2-C6H4CO2H, H2Sal) at room temperature in wet acetonitrile or nitromethane leads to the facile formation of an oxo cluster compound with formula [Bi4(m3-O)2(HSal)8] solvated by either MeCN and MeNO2 (1×2MeCN or 1×2MeNO2). This simple procedure affords a convenient, high yield (>80%) synthesis of a single bismuth oxo cluster. Both adducts exhibit a nearly planar Bi4(m3-O)2 core. The solvent ligands are situated in the same coordination sites in both but at long Bi---N and Bi---O distances. The ease of preparation as a pure compound makes this an ideal starting material for study of bismuth oxo-salicylate chemistry. | |
| dc.identifier.citation | Boyd , Tyler D., Kumar, Ish, Wagner, Eric E., et al.. "Synthesis and structural studies of the simplest bismuth(III) oxo-salicylate complex: [Bi4(m3-O)2(HO-2-C6H4CO2)8]×2 Solv (Solv = MeCN or MeNO2)." <i>Chemical Communications,</i> 50, (2014) Royal Society of Chemistry: 3556-3559. http://dx.doi.org/10.1039/C4CC00056K. | |
| dc.identifier.doi | http://dx.doi.org/10.1039/C4CC00056K | |
| dc.identifier.uri | https://hdl.handle.net/1911/76290 | |
| dc.language.iso | eng | |
| dc.publisher | Royal Society of Chemistry | |
| dc.rights | This is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by the Royal Society of Chemistry. | |
| dc.title | Synthesis and structural studies of the simplest bismuth(III) oxo-salicylate complex: [Bi4(m3-O)2(HO-2-C6H4CO2)8]×2 Solv (Solv = MeCN or MeNO2) | |
| dc.type | Journal article | |
| dc.type.dcmi | Text | |
| dc.type.publication | post-print |
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