Functional wood for carbon dioxide capture

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dc.citation.articleNumber101269en_US
dc.citation.issueNumber2en_US
dc.citation.journalTitleCell Reports Physical Scienceen_US
dc.citation.volumeNumber4en_US
dc.contributor.authorRoy, Soumyabrataen_US
dc.contributor.authorPhilip, Firuz Alamen_US
dc.contributor.authorOliveira, Eliezer Fernandoen_US
dc.contributor.authorSingh, Gurwinderen_US
dc.contributor.authorJoseph, Stalinen_US
dc.contributor.authorYadav, Ram Manoharen_US
dc.contributor.authorAdumbumkulath, Aparnaen_US
dc.contributor.authorHassan, Sakiben_US
dc.contributor.authorKhater, Alien_US
dc.contributor.authorWu, Xiaoweien_US
dc.contributor.authorBollini, Praveenen_US
dc.contributor.authorVinu, Ajayanen_US
dc.contributor.authorShimizu, Georgeen_US
dc.contributor.authorAjayan, Pulickel M.en_US
dc.contributor.authorKibria, Md Golamen_US
dc.contributor.authorRahman, Muhammad M.en_US
dc.date.accessioned2023-03-10T19:04:08Zen_US
dc.date.available2023-03-10T19:04:08Zen_US
dc.date.issued2023en_US
dc.description.abstractWith increasing global climate change, integrated concepts to innovate sustainable structures that can multiaxially address CO2 mitigation are crucial. Here, we fabricate a functional wood structure with enhanced mechanical performance via a top-down approach incorporating a high-performance metal-organic framework (MOF), Calgary framework 20 (CALF-20). The functional wood with 10% (w/w) CALF-20 can capture CO2 with an overall gravimetric capacity of 0.45 mmol/g at 1 bar and 303 K that scales linearly with the MOF loading. Interestingly, the functional wood surpasses the calculated normalized adsorption capacity of CALF-20 stemming from the mesoporous wood framework, pore geometry modulation in CALF-20, and favorable CO2 uptake interactions. Density functional theory (DFT) calculations elucidate strong interactions between CALF-20 and the cellulose backbone and an understanding of how such interactions can favorably modulate the pore geometry and CO2 physisorption energies. Thus, our work opens an avenue for developing sustainable composites that can be utilized in CO2 capture and structural applications.en_US
dc.identifier.citationRoy, Soumyabrata, Philip, Firuz Alam, Oliveira, Eliezer Fernando, et al.. "Functional wood for carbon dioxide capture." <i>Cell Reports Physical Science,</i> 4, no. 2 (2023) Cell Press: https://doi.org/10.1016/j.xcrp.2023.101269.en_US
dc.identifier.digital1-s2-0-S2666386423000280-mainen_US
dc.identifier.doihttps://doi.org/10.1016/j.xcrp.2023.101269en_US
dc.identifier.urihttps://hdl.handle.net/1911/114490en_US
dc.language.isoengen_US
dc.publisherCell Pressen_US
dc.rightsThis is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).en_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/).en_US
dc.titleFunctional wood for carbon dioxide captureen_US
dc.typeJournal articleen_US
dc.type.dcmiTexten_US
dc.type.publicationpublisher versionen_US
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