Current-Generating Double-Layer Shoe with a Porous Sole: Ion Transport Matters

dc.citation.firstpage7584en_US
dc.citation.issueNumber14en_US
dc.citation.journalTitleThe Journal of Physical Chemistry Cen_US
dc.citation.lastpage7595en_US
dc.citation.volumeNumber121en_US
dc.contributor.authorKornyshev, Alexei A.en_US
dc.contributor.authorTwidale, Rebecca M.en_US
dc.contributor.authorKolomeisky, Anatoly B.en_US
dc.contributor.orgCenter for Theoretical Biological Physicsen_US
dc.date.accessioned2017-08-02T14:52:15Zen_US
dc.date.available2017-08-02T14:52:15Zen_US
dc.date.issued2017en_US
dc.description.abstractGenerating electrical current from mechanically forced variation of the contact area of electrode/electrolyte interface underpins one of the scenarios of harvesting electrical current from walking. We develop here theory of an electrical shoe with a porous sole with an account of both convection of the liquid electrolyte under pressure and ion migration with transmission-line-type charging of electrical double layer at the pore walls. We show here that ion transport limitations can dramatically reduce the generated current and power density. The developed theory describes the time dependence of the generated current and reveals its dependence on the main operation parameters, the amplitudes of oscillating pressure and frequency, in relation to the system parameters.en_US
dc.identifier.citationKornyshev, Alexei A., Twidale, Rebecca M. and Kolomeisky, Anatoly B.. "Current-Generating Double-Layer Shoe with a Porous Sole: Ion Transport Matters." <i>The Journal of Physical Chemistry C,</i> 121, no. 14 (2017) American Chemical Society: 7584-7595. https://doi.org/10.1021/acs.jpcc.6b11385.en_US
dc.identifier.digitalTL-shoe-finalen_US
dc.identifier.doihttps://doi.org/10.1021/acs.jpcc.6b11385en_US
dc.identifier.urihttps://hdl.handle.net/1911/96166en_US
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsThis is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by the American Chemical Society.en_US
dc.titleCurrent-Generating Double-Layer Shoe with a Porous Sole: Ion Transport Mattersen_US
dc.typeJournal articleen_US
dc.type.dcmiTexten_US
dc.type.publicationpost-printen_US
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