Method of determining solid and liquid components in sedimentary rocks using NMR relaxation

Abstract

A method for separating liquid-like (T2e) from solid-like (T2G) 1H NMR transverse relaxation times in porous media uses novel pulse sequences together with a 1H NMR spectrometer optimized for geological core samples. The method is applied to obtain 1D T2 distributions and 2D T1-T2 maps in organic-rich chalks for quantification of liquid-like signal (micropore fluids, meso-macropore fluids, fluids dissolved in organic matter, and clay-bound water) and solid-like signal (kerogen, bitumen, and clay hydroxyls). The novel pulse sequences comprise a solid-echo, which detects more solid-like signal than an FID. The method is used for fluid typing in micro/meso-macro pores, clay mineral identification, determination of kerogen content, and quantification of solvent-extracted bitumen versus bitumen expelled from kerogen due to swelling from dissolved hydrocarbons. The method is used to quantify the asphaltene, resin, aromatic, and/or saturate content of bitumen in the rock.

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