Seed crystals and catalyzed epitaxy of single-walled carbon nanotubes
| dc.contributor.advisor | Smalley, Richard E. | |
| dc.creator | Wang, Yuhuang | |
| dc.date.accessioned | 2009-06-04T08:49:01Z | |
| dc.date.available | 2009-06-04T08:49:01Z | |
| dc.date.issued | 2004 | |
| dc.description.abstract | This thesis demonstrates the continued growth of single-walled carbon nanotubes (SWNTs) from seeded SWNTs in a way analogous to epitaxy or cloning; that is, the SWNTs grow as a seamless extension to the existing seeded SWNTs and have the same diameter and chirality as those of the SWNT seeds. The experiments were carried out in three key steps, including: (1) preparing a macroscopic array of open-ended SWNTs; (2) reductively docking transition metals as a catalyst to the nanometer-sized open ends; and then (3) heating the whole up to 700--850°C in the presence of a carbon feedstock such as ethanol or ethylene. The resulting SWNT ropes inherit the diameters and chirality from the seeded SWNTs, as indicated by the closely matched frequencies of Raman radial breathing modes before and after the growth. As a control, only sparse nanotubes grew from closed-ended SWNTs, ruling out spontaneous nucleation as a dominating mechanism in our experiments. This experiment proved for the first time the growth of SWNTs can be separated from the nucleation step. The ability to separate the typically inefficient nucleation step from the growth of SWNTs and to restart the growth opens the possibility of amplifying SWNTs with only the desired (n, m). The success in the continued growth was enabled with the creation of macroscopic arrays of open-ended SWNTs from a neat SWNT fiber. A variety of techniques including cryo-microtoming and surface etching chemistry have been developed to produce a macroscopic (∼1200mum2), aligned, and clean---largely free of amorphous carbon, oxides, and metal residuals---SWNT substrate with open-ended SWNTs aligned along the fiber axis. Alternatively, the fiber was milled perpendicular to the fiber axis with a gallium focused ion beam to produce a planar, free-standing, ultra-thin, "bed-of-nails" SWNT membrane---a single layer of parallel SWNTs densely packed and aligned along the normal of the membrane. | |
| dc.format.extent | 186 p. | en_US |
| dc.format.mimetype | application/pdf | |
| dc.identifier.callno | THESIS CHEM. 2005 WANG | |
| dc.identifier.citation | Wang, Yuhuang. "Seed crystals and catalyzed epitaxy of single-walled carbon nanotubes." (2004) Diss., Rice University. <a href="https://hdl.handle.net/1911/18834">https://hdl.handle.net/1911/18834</a>. | |
| dc.identifier.uri | https://hdl.handle.net/1911/18834 | |
| dc.language.iso | eng | |
| dc.rights | Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder. | |
| dc.subject | Chemistry | |
| dc.subject | Molecular physics | |
| dc.subject | Engineering | |
| dc.subject | Materials science | |
| dc.title | Seed crystals and catalyzed epitaxy of single-walled carbon nanotubes | |
| dc.type | Thesis | |
| dc.type.material | Text | |
| thesis.degree.department | Chemistry | |
| thesis.degree.discipline | Natural Sciences | |
| thesis.degree.grantor | Rice University | |
| thesis.degree.level | Doctoral | |
| thesis.degree.name | Doctor of Philosophy |
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