Solubility and rheological examination of buckminsterfullerene in decalin and PSVS
| dc.contributor.advisor | Barrera, Enrique V. | en_US |
| dc.creator | Lozano, Karen | en_US |
| dc.date.accessioned | 2009-06-04T00:34:02Z | en_US |
| dc.date.available | 2009-06-04T00:34:02Z | en_US |
| dc.date.issued | 1996 | en_US |
| dc.description.abstract | The structure-property relationships of C$\sb{60}$ dissolved in decahydronaphtalene (decalin) and a petroleum solvent viscous standard (PSVS) were studied. This work was motivated mainly by the interest to improve fullerene dispersion in powder processing and the development of a viscoelastic standard for commercial use. Decalin was selected based on the amount of fullerene it can hold, the toxicity grade, rate of evaporation, and inability to interfere with the test method. The PSVS is a standard for viscous calibration of rheological instruments. Measurements of solubility, density, viscosity and elasticity values were conducted. The results are for samples classified as 0, 25, 50, 75 and 100% of C$\sb{60}$ saturation level. Decalin can dissolve 1.9 mg/ml of C$\sb{60}$ while the PSVS only dissolves 0.15 mg/ml. The viscosity behavior shown by both solvents was Newtonian, with a small increase in viscosity as a function of fullerene concentration. The elastic portion of the solvents did not change with fullerene concentration. | en_US |
| dc.format.extent | 78 p. | en_US |
| dc.format.mimetype | application/pdf | en_US |
| dc.identifier.callno | THESIS M.E. 1996 LOZANO | en_US |
| dc.identifier.citation | Lozano, Karen. "Solubility and rheological examination of buckminsterfullerene in decalin and PSVS." (1996) Master’s Thesis, Rice University. <a href="https://hdl.handle.net/1911/14086">https://hdl.handle.net/1911/14086</a>. | en_US |
| dc.identifier.uri | https://hdl.handle.net/1911/14086 | en_US |
| dc.language.iso | eng | en_US |
| dc.rights | Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder. | en_US |
| dc.subject | Engineering | en_US |
| dc.subject | Materials science | en_US |
| dc.subject | Chemical engineering | en_US |
| dc.title | Solubility and rheological examination of buckminsterfullerene in decalin and PSVS | en_US |
| dc.type | Thesis | en_US |
| dc.type.material | Text | en_US |
| thesis.degree.department | Mechanical Engineering | en_US |
| thesis.degree.discipline | Engineering | en_US |
| thesis.degree.grantor | Rice University | en_US |
| thesis.degree.level | Masters | en_US |
| thesis.degree.name | Master of Science | en_US |
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