Part I. The radical chemistry of geminal bis-azoalkanes. Part II. The radical chemistry of vicinal bis-azoalkanes. Part III. Homolysis of a weak carbon-carbon bond
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Part I. The radical chemistry of geminal bis-azoalkanes. Two geminal bis-azoalkanes have been employed to generate carbon centered radicals adjacent to azo substituents. The activation free energies for C-N bond homolysis of 2,2-bis-(phenylazo)propane (1) and 2-methylazo-2-phenylazopropane (2) were 8 kcal/mol lower than for the corresponding model compounds 3-methyl-3-phenylazo-1-butene (4) and 3-methyl-3-methylazo-1-butene (5). This large rate enhancing effect of an
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Chen, Yanqiu. "Part I. The radical chemistry of geminal bis-azoalkanes. Part II. The radical chemistry of vicinal bis-azoalkanes. Part III. Homolysis of a weak carbon-carbon bond." (1989) Diss., Rice University. https://hdl.handle.net/1911/16217.