Corresponding states correlations relating proton spin-lattice relaxation rates of hydrocarbons to viscosities at advanced pressures

dc.contributor.advisorKobayashi, Rikien_US
dc.creatorBeznik, Frantzen_US
dc.date.accessioned2009-06-04T00:13:40Zen_US
dc.date.available2009-06-04T00:13:40Zen_US
dc.date.issued1994en_US
dc.description.abstractA new five-parameter corresponding states model has been developed for viscosity and proton spin-lattice relaxation rate applicable to a variety of hydrocarbons in the dense fluid phase region. This model is the key to the development of unprecedented, accurate correlations between the proton spin-lattice relaxation rate, R$\sb1$, and the viscosity, $\eta$, of pure hydrocarbons, with an observed root-mean-square deviations of less than 8.0%. For hydrocarbon mixtures, the notion of "effective" spin-lattice relaxation rate, introduced by Zega et al$\sp{1,2}$, is pursued. Then, simple mixing rules are successfully applied to extend the model to mixtures. The four-parameter corresponding states treatment, utilizing the shape factors as proposed by Leach and Leland$\sp3$, yields correlations of comparable accuracy, when confined to long-chain alkanes.en_US
dc.format.extent142 p.en_US
dc.format.mimetypeapplication/pdfen_US
dc.identifier.callnoTHESIS CH.E. 1994 BEZNIKen_US
dc.identifier.citationBeznik, Frantz. "Corresponding states correlations relating proton spin-lattice relaxation rates of hydrocarbons to viscosities at advanced pressures." (1994) Master’s Thesis, Rice University. <a href="https://hdl.handle.net/1911/13814">https://hdl.handle.net/1911/13814</a>.en_US
dc.identifier.urihttps://hdl.handle.net/1911/13814en_US
dc.language.isoengen_US
dc.rightsCopyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder.en_US
dc.subjectChemical engineeringen_US
dc.titleCorresponding states correlations relating proton spin-lattice relaxation rates of hydrocarbons to viscosities at advanced pressuresen_US
dc.typeThesisen_US
dc.type.materialTexten_US
thesis.degree.departmentChemical Engineeringen_US
thesis.degree.disciplineEngineeringen_US
thesis.degree.grantorRice Universityen_US
thesis.degree.levelMastersen_US
thesis.degree.nameMaster of Scienceen_US
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