Photolysis of azoalkanes. Reactions and kinetics of the 1-cyclopropyl-1,3-cyclopentanediyl biradical and 1-cyclopropylcyclopentyl radical
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The 1-cyclopropylcyclopentyl radical (114a) and 1-cyclopropylcyclohexyl radical (114b) were generated in the presence of PhSH via 366 nm photolysis of azo-1-cyclopropylcyclopentane and azo-1-cyclopropylcyclohexane respectively. These radicals undergo cyclopropylcarbinyl (CPC) rearrangement to primary homoallylic radicals 115a and 115b, respectively, at rates of 1.45
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Culotta, Anne Marie. "Photolysis of azoalkanes. Reactions and kinetics of the 1-cyclopropyl-1,3-cyclopentanediyl biradical and 1-cyclopropylcyclopentyl radical." (1991) Diss., Rice University. https://hdl.handle.net/1911/16434.