Matrix reactions of silicon difluoride as studied by infrared spectroscopy

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dc.contributor.advisorMargrave, John L.en_US
dc.creatorBassler, Jouette McCurdyen_US
dc.date.accessioned2016-04-21T12:01:14Zen_US
dc.date.available2016-04-21T12:01:14Zen_US
dc.date.issued1966en_US
dc.description.abstractInfrared matrix isolation spectroscopy has been employed to characterize monomeric silicon difluoride. Warm-up experiments show the development of several sets of new bands which indicate that this molecule polymerizes through a reactive dimeric intermediate. Other reactive molecules were mixed with the matrix gas and deposited with silicon difluoride on the cold window. When these heterogeneous matrices were allowed to warm up, new bands characteristic of the reaction products of silicon difluoride with the secondary species were observed to appear. In this manner the reactions of silicon difluoride with boron trifluoride, carbon monoxide, nitric oxide, oxygen and perfluorobenzene were observed and the reaction products spectroscopically identified.en_US
dc.format.digitalOriginreformatted digitalen_US
dc.format.extent63 ppen_US
dc.identifier.callnoThesis Chem. 1966 Bassleren_US
dc.identifier.citationBassler, Jouette McCurdy. "Matrix reactions of silicon difluoride as studied by infrared spectroscopy." (1966) Master’s Thesis, Rice University. <a href="https://hdl.handle.net/1911/89054">https://hdl.handle.net/1911/89054</a>.en_US
dc.identifier.digitalRICE0089en_US
dc.identifier.urihttps://hdl.handle.net/1911/89054en_US
dc.language.isoengen_US
dc.rightsCopyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder.en_US
dc.titleMatrix reactions of silicon difluoride as studied by infrared spectroscopyen_US
dc.typeThesisen_US
dc.type.materialTexten_US
thesis.degree.departmentChemistryen_US
thesis.degree.disciplineNatural Sciencesen_US
thesis.degree.grantorRice Universityen_US
thesis.degree.levelMastersen_US
thesis.degree.nameMaster of Artsen_US
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