Matrix reactions of silicon difluoride as studied by infrared spectroscopy

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dc.contributor.advisorMargrave, John L.
dc.creatorBassler, Jouette McCurdy
dc.date.accessioned2016-04-21T12:01:14Z
dc.date.available2016-04-21T12:01:14Z
dc.date.issued1966
dc.description.abstractInfrared matrix isolation spectroscopy has been employed to characterize monomeric silicon difluoride. Warm-up experiments show the development of several sets of new bands which indicate that this molecule polymerizes through a reactive dimeric intermediate. Other reactive molecules were mixed with the matrix gas and deposited with silicon difluoride on the cold window. When these heterogeneous matrices were allowed to warm up, new bands characteristic of the reaction products of silicon difluoride with the secondary species were observed to appear. In this manner the reactions of silicon difluoride with boron trifluoride, carbon monoxide, nitric oxide, oxygen and perfluorobenzene were observed and the reaction products spectroscopically identified.
dc.format.digitalOriginreformatted digitalen_US
dc.format.extent63 ppen_US
dc.identifier.callnoThesis Chem. 1966 Bassleren_US
dc.identifier.citationBassler, Jouette McCurdy. "Matrix reactions of silicon difluoride as studied by infrared spectroscopy." (1966) Master’s Thesis, Rice University. <a href="https://hdl.handle.net/1911/89054">https://hdl.handle.net/1911/89054</a>.
dc.identifier.digitalRICE0089en_US
dc.identifier.urihttps://hdl.handle.net/1911/89054
dc.language.isoeng
dc.rightsCopyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder.
dc.titleMatrix reactions of silicon difluoride as studied by infrared spectroscopy
dc.typeThesis
dc.type.materialText
thesis.degree.departmentChemistry
thesis.degree.disciplineNatural Sciences
thesis.degree.grantorRice University
thesis.degree.levelMasters
thesis.degree.nameMaster of Arts
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