Large-scale production and purification of single-walled carbon nanotubes

Date
1999
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Abstract

Single Walled Nanotubes were produced in large scale by Laser Vaporization with maximum yields of 50%. Optimization experiments give relative yields of (Nickel Cobalt (1:1 atomic % each)) = (Nickel Tungsten (1:1)) > (Nickel Yttrium (1.6:0.4)/Cobalt Platinum (0.9:0.3)) > (Nickel Platinum (0.9:0.3)/Cobalt Platinum (1:1)/Nickel Yttrium (4.2:1)/Nickel Molybdenum (1:1)) (Ruthenium (0.5)). For changes in atmosphere the yields are Argon (500 torr) = Carbon Monoxide (700 torr) = Argon (700 torr) Helium (500 torr). Differences in yields are discussed and compared to results from the electric arc technique. The setup has been successfully scaled-up and operates for more than 36 hours. The target preparation and SWNT material purification procedures have been optimized and scaled-up accordingly to obtain grams of 95% pure SWNT routinely. High quality material is now available, from a facility called "tubes@rice", for research purposes.

Description
Degree
Master of Arts
Type
Thesis
Keywords
Physical chemistry, Chemical engineering, Engineering, Materials science
Citation

Rodriguez-Macias, Fernando J.. "Large-scale production and purification of single-walled carbon nanotubes." (1999) Master’s Thesis, Rice University. https://hdl.handle.net/1911/17294.

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