Chemical reactions at high pressures and high temperatures

dc.contributor.advisorMargrave, John L.en_US
dc.creatorChang, Chin-Hsiungen_US
dc.date.accessioned2007-05-09T18:38:39Zen_US
dc.date.available2007-05-09T18:38:39Zen_US
dc.date.issued1967en_US
dc.description.abstractTwo high pressure devices, the opposed anvil and the tetrahedral anvil, have been used for studying chemical reactions at high pressures and high temperatures. The effect of pressure on the thermal decomposition of potassium chlorate and mercuric oxide has been determined experimentally. New cubic mercury and cadmium metaborates were isolated and studied. Group III superoxides have been synthesized under high pressures and their properties have been investigated by x-ray, infrared, electron spin resonance and chemical methods. Three new high pressure forms of LiMO2(M = B, Al and Ga)-compounds have been synthesized and identified. It is found that y-LiB02 and y-LiA10 could be synthesized directly by reacting lithium peroxide with boric oxide and aluminum oxide respectively.en_US
dc.format.digitalOriginreformatted digitalen_US
dc.format.extent214 ppen_US
dc.format.mimetypeapplication/pdfen_US
dc.identifier.callnoThesis Chem. 1967 Changen_US
dc.identifier.citationChang, Chin-Hsiung. "Chemical reactions at high pressures and high temperatures." (1967) Diss., Rice University. <a href="https://hdl.handle.net/1911/14334">https://hdl.handle.net/1911/14334</a>.en_US
dc.identifier.digitalRICE0067en_US
dc.identifier.urihttps://hdl.handle.net/1911/14334en_US
dc.language.isoengen_US
dc.rightsCopyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder.en_US
dc.subjectPhysical chemistryen_US
dc.titleChemical reactions at high pressures and high temperaturesen_US
dc.typeThesisen_US
dc.type.materialTexten_US
thesis.degree.departmentChemistryen_US
thesis.degree.disciplineNatural Sciencesen_US
thesis.degree.grantorRice Universityen_US
thesis.degree.levelDoctoralen_US
thesis.degree.nameDoctor of Philosophyen_US
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