Photocycloaddition of quinones to olefins: Mechanism and applications

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dc.contributor.advisorCiufolini, Marco A.en_US
dc.creatorRivera Fortin, Maria Angelicaen_US
dc.date.accessioned2009-06-03T23:58:06Zen_US
dc.date.available2009-06-03T23:58:06Zen_US
dc.date.issued1993en_US
dc.description.abstractPhotochemical reactions between benzoquinones and alkylidenecyclohexanes proceed regioselectively. Regioselectivity is determined by the conformational properties of the cyclic olefin. Photocycloadducts thus obtained may be used for the construction of important alkaloidal frameworks in synthetically useful yields. Oxetane formation is likely to occur through concerted collapse of an exciplex that possesses considerable charge transfer character.en_US
dc.format.extent209 p.en_US
dc.format.mimetypeapplication/pdfen_US
dc.identifier.callnoThesis Chem. 1993 Rivera Fortien_US
dc.identifier.citationRivera Fortin, Maria Angelica. "Photocycloaddition of quinones to olefins: Mechanism and applications." (1993) Master’s Thesis, Rice University. <a href="https://hdl.handle.net/1911/13773">https://hdl.handle.net/1911/13773</a>.en_US
dc.identifier.urihttps://hdl.handle.net/1911/13773en_US
dc.language.isoengen_US
dc.rightsCopyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder.en_US
dc.subjectOrganic chemistryen_US
dc.titlePhotocycloaddition of quinones to olefins: Mechanism and applicationsen_US
dc.typeThesisen_US
dc.type.materialTexten_US
thesis.degree.departmentChemistryen_US
thesis.degree.disciplineNatural Sciencesen_US
thesis.degree.grantorRice Universityen_US
thesis.degree.levelMastersen_US
thesis.degree.nameMaster of Artsen_US
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