Continuously-scanned Raman excitation profiles for ozone excited in the Hartley band

Simple item page
dc.contributor.advisorKinsey, James L.en_US
dc.creatorHsiao, Chih-Weien_US
dc.date.accessioned2009-06-04T08:38:08Zen_US
dc.date.available2009-06-04T08:38:08Zen_US
dc.date.issued2000en_US
dc.description.abstractImprovements in the determination of the continuously-scanned Raman excitation profiles (REP's) are described. The continuous-scanning technique is applied to ozone excited in the first continuum (the Hartley band). The Rayleigh excitation profile, which is required for intensity calibration, is obtained simultaneously. A theoretical calculation for the ozone Rayleigh excitation profile is also provided for comparison. REP measurements of the vibrational features up to 6 quanta are determined in the wavelength range of 238--271 nm. These spectra show oscillatory structures that are qualitatively but unambiguously identified as the Raman counterparts of those in the absorption spectrum. The use of overlapping dye mixtures to cover most of the Hartley band is required. Difficulties encountered in patching together these first-generation spectra are discussed in detail.en_US
dc.format.extent141 p.en_US
dc.format.mimetypeapplication/pdfen_US
dc.identifier.callnoTHESIS CHEM. 2000 HSIAOen_US
dc.identifier.citationHsiao, Chih-Wei. "Continuously-scanned Raman excitation profiles for ozone excited in the Hartley band." (2000) Diss., Rice University. <a href="https://hdl.handle.net/1911/19508">https://hdl.handle.net/1911/19508</a>.en_US
dc.identifier.urihttps://hdl.handle.net/1911/19508en_US
dc.language.isoengen_US
dc.rightsCopyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder.en_US
dc.subjectPhysical chemistryen_US
dc.titleContinuously-scanned Raman excitation profiles for ozone excited in the Hartley banden_US
dc.typeThesisen_US
dc.type.materialTexten_US
thesis.degree.departmentChemistryen_US
thesis.degree.disciplineNatural Sciencesen_US
thesis.degree.grantorRice Universityen_US
thesis.degree.levelDoctoralen_US
thesis.degree.nameDoctor of Philosophyen_US
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
9969268.PDF
Size:
3.65 MB
Format:
Adobe Portable Document Format
Download
Collections
Rice University Theses and Dissertations