Development of New Methods for the Synthesis of Novel Biaryls

Simple item page
dc.contributor.advisorKurti, Laszlo
dc.creatorKeene, Craig Allen
dc.date.accessioned2017-08-01T16:18:15Z
dc.date.available2017-08-01T16:18:15Z
dc.date.created2017-05
dc.date.issued2016-12-13
dc.date.submittedMay 2017
dc.date.updated2017-08-01T16:18:15Z
dc.description.abstractHerein the first organocatalytic atroposelective synthesis of BINAM derivatives is detailed. The findings of which inspired the development of new methodology directed toward the synthesis of 3-substituted-2-nitronaphthalene building blocks. The nitronaphthalenes were then utilized in a new approach aimed at the synthesis of symmetrical and unsymmetrical diaryl hydrazines. A novel approach for the synthesis of functionalized, non-C2-symmetric, atropisomeric biaryls in a one-pot transformation is also described.
dc.format.mimetypeapplication/pdf
dc.identifier.citationKeene, Craig Allen. "Development of New Methods for the Synthesis of Novel Biaryls." (2016) Diss., Rice University. <a href="https://hdl.handle.net/1911/96002">https://hdl.handle.net/1911/96002</a>.
dc.identifier.urihttps://hdl.handle.net/1911/96002
dc.language.isoeng
dc.rightsCopyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder.
dc.subjectbiaryl
dc.subjecttriaryl
dc.subjectnitronaphthalene
dc.subjectnitrostyrene
dc.subjectamide oxidation
dc.subjectaxial-chirality
dc.subject2-naphthylamine
dc.titleDevelopment of New Methods for the Synthesis of Novel Biaryls
dc.typeThesis
dc.type.materialText
thesis.degree.departmentChemistry
thesis.degree.disciplineNatural Sciences
thesis.degree.grantorRice University
thesis.degree.levelDoctoral
thesis.degree.majorOrganic Chemistry
thesis.degree.nameDoctor of Philosophy
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
KEENE-DOCUMENT-2017.pdf
Size:
18.59 MB
Format:
Adobe Portable Document Format
Description:
Download
License bundle
Now showing 1 - 2 of 2
No Thumbnail Available
Name:
PROQUEST_LICENSE.txt
Size:
5.84 KB
Format:
Plain Text
Description:
Download
No Thumbnail Available
Name:
LICENSE.txt
Size:
2.6 KB
Format:
Plain Text
Description:
Download
Collections
Rice University Electronic Theses and Dissertations