Development of New Methods for the Synthesis of Novel Biaryls

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dc.contributor.advisorKurti, Laszloen_US
dc.creatorKeene, Craig Allenen_US
dc.date.accessioned2017-08-01T16:18:15Zen_US
dc.date.available2017-08-01T16:18:15Zen_US
dc.date.created2017-05en_US
dc.date.issued2016-12-13en_US
dc.date.submittedMay 2017en_US
dc.date.updated2017-08-01T16:18:15Zen_US
dc.description.abstractHerein the first organocatalytic atroposelective synthesis of BINAM derivatives is detailed. The findings of which inspired the development of new methodology directed toward the synthesis of 3-substituted-2-nitronaphthalene building blocks. The nitronaphthalenes were then utilized in a new approach aimed at the synthesis of symmetrical and unsymmetrical diaryl hydrazines. A novel approach for the synthesis of functionalized, non-C2-symmetric, atropisomeric biaryls in a one-pot transformation is also described.en_US
dc.format.mimetypeapplication/pdfen_US
dc.identifier.citationKeene, Craig Allen. "Development of New Methods for the Synthesis of Novel Biaryls." (2016) Diss., Rice University. <a href="https://hdl.handle.net/1911/96002">https://hdl.handle.net/1911/96002</a>.en_US
dc.identifier.urihttps://hdl.handle.net/1911/96002en_US
dc.language.isoengen_US
dc.rightsCopyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder.en_US
dc.subjectbiarylen_US
dc.subjecttriarylen_US
dc.subjectnitronaphthaleneen_US
dc.subjectnitrostyreneen_US
dc.subjectamide oxidationen_US
dc.subjectaxial-chiralityen_US
dc.subject2-naphthylamineen_US
dc.titleDevelopment of New Methods for the Synthesis of Novel Biarylsen_US
dc.typeThesisen_US
dc.type.materialTexten_US
thesis.degree.departmentChemistryen_US
thesis.degree.disciplineNatural Sciencesen_US
thesis.degree.grantorRice Universityen_US
thesis.degree.levelDoctoralen_US
thesis.degree.majorOrganic Chemistryen_US
thesis.degree.nameDoctor of Philosophyen_US
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