Synthesis of functionalized naphthalenes
| dc.contributor.advisor | Billings, W. E. | en_US |
| dc.contributor.committeeMember | Engel, Paul S. | en_US |
| dc.contributor.committeeMember | Lewis, Edward S. | en_US |
| dc.creator | Lewis, Linda Kay | en_US |
| dc.date.accessioned | 2018-12-18T21:24:26Z | en_US |
| dc.date.available | 2018-12-18T21:24:26Z | en_US |
| dc.date.issued | 1983 | en_US |
| dc.description.abstract | 1,2 and 2,3-disubstituted naphthalenes were synthesized by carbene addition to substituted indenes. The indene precursors were formed by two methods: Grignard addition to indanones with elimination and by the reaction of indanones with phosphorus pentahalide. The carbene addition to indene was facilitated fcy the use of a micellar phase transfer catalyst, hexadecyltrimethyl ammonium branide. This catalyst allowed carbene addition to double bonds with both electron donating and withdrawing substituents. The naphthalenes formed by this method include: 2-chloro-3-methylnaphthalene, 2-chloro-3-phenylnaphthalene, 1,2-dichloronaphthalene, 2-chloro-l-phenylnaphthalene, 2-brano-3chloronaphthalene and 2,3-dichioronaphthalene. | en_US |
| dc.format.digitalOrigin | reformatted digital | en_US |
| dc.format.extent | 38 pp | en_US |
| dc.identifier.callno | Thesis Chem. 1983 Lewis | en_US |
| dc.identifier.citation | Lewis, Linda Kay. "Synthesis of functionalized naphthalenes." (1983) Master’s Thesis, Rice University. <a href="https://hdl.handle.net/1911/104507">https://hdl.handle.net/1911/104507</a>. | en_US |
| dc.identifier.digital | RICE2142 | en_US |
| dc.identifier.uri | https://hdl.handle.net/1911/104507 | en_US |
| dc.language.iso | eng | en_US |
| dc.rights | Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder. | en_US |
| dc.title | Synthesis of functionalized naphthalenes | en_US |
| dc.type | Thesis | en_US |
| dc.type.material | Text | en_US |
| thesis.degree.department | Chemistry | en_US |
| thesis.degree.discipline | Natural Sciences | en_US |
| thesis.degree.grantor | Rice University | en_US |
| thesis.degree.level | Masters | en_US |
| thesis.degree.name | Master of Arts | en_US |
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