The photochemistry of (alpha)-acetylenic ketones

dc.contributor.advisorEngel, Paul S.en_US
dc.creatorSchroeder, Myron Eugeneen_US
dc.date.accessioned2018-12-18T21:23:00Zen_US
dc.date.available2018-12-18T21:23:00Zen_US
dc.date.issued1977en_US
dc.description.abstractAn investigation of the photochemistry of several a-acetylenic ketones was instituted. The photochemical behavior of 2-octyne-4-one 22 was compared with that of 2-octene-4-one 2j. Whereas the latter underwent only cis-trans olefin isomerization, the former proceeded efficiently to y-hydrogen abstraction products. Both photochemical and spectroscopic properties of 22. reveal its similarity to valerophenone 58. 4,4-dimethyl-1hexyne-3-one 23 was synthesized in order to study a-methyl effects in the photochemistry of ynones. 4,4-dimethyllhexyne-5-ene-3-one 24^ was also synthesized and a preliminary inspection of the photochemistry of 23. and 24 was made.en_US
dc.format.digitalOriginreformatted digitalen_US
dc.format.extent86 ppen_US
dc.identifier.callnoThesis Chem. 1977 Schroederen_US
dc.identifier.citationSchroeder, Myron Eugene. "The photochemistry of (alpha)-acetylenic ketones." (1977) Master’s Thesis, Rice University. <a href="https://hdl.handle.net/1911/104432">https://hdl.handle.net/1911/104432</a>.en_US
dc.identifier.digitalRICE2067en_US
dc.identifier.urihttps://hdl.handle.net/1911/104432en_US
dc.language.isoengen_US
dc.rightsCopyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder.en_US
dc.titleThe photochemistry of (alpha)-acetylenic ketonesen_US
dc.typeThesisen_US
dc.type.materialTexten_US
thesis.degree.departmentChemistryen_US
thesis.degree.disciplineNatural Sciencesen_US
thesis.degree.grantorRice Universityen_US
thesis.degree.levelMastersen_US
thesis.degree.nameMaster of Artsen_US
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