Cyclopropanation of dienol ethers
Date
1977
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Abstract
The copper-catalysed, thermal decompositions of ethyl diazoacetate and diazoacetone in the presence of 1-methoxycyclohexa-1,3-diene, l-methoxy-4-methylcyclohexa-l,3-diene, 1-methoxybuta-l,3-diene, 1-ethoxybuta-l,3-diene and 1-trimethylsilyloxybuta-1,3-diene and the acid hydrolysis of the resultant cyclopropanes are described. These reactions constitute a simple, two-step procedure for the production of olefinic 1,4- and 1,6-dicarbonyl compounds, starting from dienol ethers of a,g -unsaturated aldehydes and ketones.
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Text includes handwritten formulas
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Degree
Master of Arts
Type
Thesis
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Citation
Ranu, Brindaban Chandra. "Cyclopropanation of dienol ethers." (1977) Master’s Thesis, Rice University. https://hdl.handle.net/1911/104479.
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