The effect of ring size on the thermal rearrangements of bicyclo[n.1.0] alka-1, n-dienes
| dc.contributor.advisor | Billings, W. E. | en_US |
| dc.creator | Baker, Brian Austin | en_US |
| dc.date.accessioned | 2018-12-18T21:22:18Z | en_US |
| dc.date.available | 2018-12-18T21:22:18Z | en_US |
| dc.date.issued | 1974 | en_US |
| dc.description.abstract | The ring expansion synthesis of cycloundacene from cyclooctene Is described» Addition of dlbromocarbene, elimination/rearrangement by n-BuLl to an aliene, and Na/NH reduction results In the formation of the next larger cycloolefin. The synthesis and rearrangements of the title compounds n-7-1 are discussed. Compound 7 rearranges exclusively to 3-methylene-1,4-cyclononadiene. Compounds 9 & 1 rearrange to 4-methylenebicyolo. Compound 8 rearranges to a 1-2 mixture of 3-methylene-l-4-cyclodecadiene and 4-methylenebicyclo deca-2-ene respectively. This is the slowest material to rearrange requiring sixteen hours at xylene reflux whereas the others rearrange within several hours in toluene reflux. | en_US |
| dc.format.digitalOrigin | reformatted digital | en_US |
| dc.format.extent | 57 pp | en_US |
| dc.identifier.callno | Thesis Chem. 1974 Baker | en_US |
| dc.identifier.citation | Baker, Brian Austin. "The effect of ring size on the thermal rearrangements of bicyclo[n.1.0] alka-1, n-dienes." (1974) Master’s Thesis, Rice University. <a href="https://hdl.handle.net/1911/104394">https://hdl.handle.net/1911/104394</a>. | en_US |
| dc.identifier.digital | RICE2029 | en_US |
| dc.identifier.uri | https://hdl.handle.net/1911/104394 | en_US |
| dc.language.iso | eng | en_US |
| dc.rights | Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder. | en_US |
| dc.title | The effect of ring size on the thermal rearrangements of bicyclo[n.1.0] alka-1, n-dienes | en_US |
| dc.type | Thesis | en_US |
| dc.type.material | Text | en_US |
| thesis.degree.department | Chemistry | en_US |
| thesis.degree.discipline | Natural Sciences | en_US |
| thesis.degree.grantor | Rice University | en_US |
| thesis.degree.level | Masters | en_US |
| thesis.degree.name | Master of Arts | en_US |
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