Browsing by Author "Wang, C.H."
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Item Dynamics of heavy-Rydberg ion-pair formation in K(14p,20p)-SF6, CCl4ᅠcollisions(AIP Publishing, 2014) Wang, C.H.; Kelley, M.; Buathong, S.; Dunning, F.B.The dynamics of formation of heavy-Rydberg ion-pair states throughᅠelectron transferᅠin K(np)-SF6, CCl4ᅠcollisions is examined byᅠmeasuringᅠtheᅠvelocity,ᅠangular, and bindingᅠenergyᅠdistributions of the product ion pairs. The results areᅠanalyzedᅠwith the aid of a Monte Carlo collision code that models both the initial electron capture and the subsequent evolution of the ion pairs. The model simulations are in good agreement with the experimental data and highlight the factors such asᅠRydberg atomᅠsize, the kineticᅠenergyᅠof relativeᅠmotionᅠof theᅠRydberg atomᅠand target particle, and (in the case of attaching targets that dissociate) the energetics ofᅠdissociationᅠthat can be used to control the properties of the product ion-pair states.