Browsing by Author "Tong, Yao"
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Item Compact and sensitive mid-infrared all-fiber quartz-enhanced photoacoustic spectroscopy sensor for carbon monoxide detection(Optical Society of America, 2019) Ma, Yufei; Tong, Yao; He, Ying; Jin, Xingang; Tittel, Frank K.A compact and sensitive quartz-enhanced photoacoustic spectroscopy (QEPAS) based sensor for carbon monoxide (CO) detection was demonstrated by using a mid-infrared all-fiber structure as well as a 3D-printed acoustic detection module. An all-fiber configuration has advantages of easier optical alignment, lower insertion loss, improvement in system stability, reduction in sensor size and lower cost. The 3D-printed acoustic detection module was introduced to match the mid-infrared all-fiber structure and further decrease the sensor volume, which resulted in a small size of 3.5 cm3 and a weight of 5 grams. A 2.33 μm distributed feedback fiber-coupled diode laser was used as the laser excitation source. A custom quartz tuning fork (QTF) with a small-gap of 200 μm was used as the acoustic wave transducer in order to improve the signal level of the QEPAS sensor. An acoustic micro resonator was utilized as the acoustic wave enhancer. The gas pressure and laser wavelength modulation depth were optimized, respectively. Water vapor was used to accelerate the vibrational-translational relaxation rate of the targeted CO molecule. Finally, a minimum detection limit (MDL) of 4.2 part per million (ppm) was achieved, corresponding to a normalized noise equivalent absorption (NNEA) coefficient of 7.4 × 10−9 cm−1W/√Hz. An Allan deviation analysis was used to evaluate the long-term stability of the reported CO-QEPAS sensor system. With an integration time of 150 s, the MDL was improved to be 1.3 ppm.Item HCN ppt-level detection based on a QEPAS sensor with amplified laser and a miniaturized 3D-printed photoacoustic detection channel(Optical Society of America, 2018) He, Ying; Ma, Yufei; Tong, Yao; Yu, Xin; Tittel, Frank K.Ultra-high sensitive and stable detection of hydrogen cyanide (HCN) based on a quartz-enhanced photoacoustic spectroscopy (QEPAS) sensor was realized using an erbium-doped fiber amplifier (EDFA) as well as a miniaturized 3D-printed photoacoustic detection channel (PADC) for the first time. A HCN molecule absorption line located at 6536.46 cm-1 was selected which was in the range of the EDFA emission spectrum. The detection sensitivity of the reported EDFA-QEPAS sensor was enhanced significantly due to the high available EDFA excitation laser power. A 3D printing technique was used to develop the compact PADC, resulting in a size of 29 × 15 × 8 mm3 and a mass of ~5 g in order to improve the sensor stability and implement sensor applications requiring a compact size and light weight. At atmospheric pressure, room temperature and a 1 s acquisition time, a minimum detection limit (MDL) of 29 parts per billion (ppb) was achieved, corresponding to a normalized noise equivalent absorption (NNEA) coefficient of 1.08 × 10-8 cm-1W/Hz-1/2. The long-term performance and the stability of the HCN EDFA-QEPAS sensor system were investigated using an Allan deviation analysis. It indicated that the MDL can be improved to 220 parts per trillion (ppt) with an integration time of 300 s, which demonstrated this compact, integrated and miniaturized 3D-printed PADC based sensor had an excellent stability.Item High-Power DFB Diode Laser-Based CO-QEPAS Sensor: Optimization and Performance(MDPI, 2018) Ma, Yufei; Tong, Yao; He, Ying; Yu, Xin; Tittel, Frank K.A highly sensitive carbon monoxide (CO) trace gas sensor based on quartz-enhanced photoacoustic spectroscopy (QEPAS) was demonstrated. A high-power distributed feedback (DFB), continuous wave (CW) 2.33 μm diode laser with an 8.8 mW output power was used as the QEPAS excitation source. By optimizing the modulation depth and adding an optimum micro-resonator, compared to a bare quartz tuning fork (QTF), a 10-fold enhancement of the CO-QEPAS signal amplitude was achieved. When water vapor acting as a vibrational transfer catalyst was added to the target gas, the signal was further increased by a factor of ~7. A minimum detection limit (MDL) of 11.2 ppm and a calculated normalized noise equivalent absorption (NNEA) coefficient of 1.8 × 10−5 cm−1W/√Hz were obtained for the reported CO-QEPAS sensor.Item Long distance, distributed gas sensing based on micro-nano fiber evanescent wave quartz-enhanced photoacoustic spectroscopy(AIP Publishing LLC, 2017) He, Ying; Ma, Yufei; Tong, Yao; Yu, Xin; Peng, Zhenfang; Gao, Jing; Tittel, Frank K.A long distance, distributed gas sensing using the micro-nano fiber evanescent wave (FEW) quartz enhanced photoacoustic spectroscopy technique was demonstrated. Such a sensor scheme has the advantages of higher detection sensitivity, distributed gas sensing ability, lower cost, and a simpler fabrication procedure compared to conventional FEW gas sensors using a photonic crystal fiber or a tapered fiber with chemical sputtering. A 3 km single mode fiber with multiple tapers and an erbium doped fiber amplifier with an output optical power of 700 mW were employed to perform long distance, distributed gas measurements.Item Long distance, distributed gas sensing based on micro-nano fiber evanescent wave quartz-enhanced photoacoustic spectroscopy(AIP Publishing, 2017) He, Ying; Ma, Yufei; Tong, Yao; Yu, Xin; Peng, Zhenfang; Gao, Jing; Tittel, Frank K.A long distance, distributed gas sensing using the micro-nano fiber evanescent wave (FEW) quartz enhanced photoacoustic spectroscopy technique was demonstrated. Such a sensor scheme has the advantages of higher detection sensitivity, distributed gas sensing ability, lower cost, and a simpler fabrication procedure compared to conventional FEW gas sensors using a photonic crystal fiber or a tapered fiber with chemical sputtering. A 3 km single mode fiber with multiple tapers and an erbium doped fiber amplifier with an output optical power of 700 mW were employed to perform long distance, distributed gas measurements.Item Ppb-level detection of ammonia based on QEPAS using a power amplified laser and a low resonance frequency quartz tuning fork(The Optical Society, 2017) Ma, Yufei; He, Ying; Tong, Yao; Yu, Xin; Tittel, Frank K.In this report, an ultra-high sensitive quartz-enhanced photoacoustic spectroscopy (QEPAS) based ammonia (NH3) sensor using a power amplified diode laser and a low resonance frequency quartz tuning fork (QTF) was demonstrated for the first time. A fiber-coupled, continuous wave (CW), distributed feedback (DFB) diode laser with a watt level output power boosted by an erbium-doped fiber amplifier (EDFA) was used as the QEPAS excitation source. A QTF with a resonance frequency of 30.72 kHz was employed as an acoustic wave transducer. The modulation depth in the wavelength modulation spectroscopy (WMS) based QEPAS system was optimized theoretically and validated by experimental measurements. For the reported NH3 sensor system, a 418.4 ppbv (parts per billion by volume) minimum detection limit at a NH3 absorption line of 6533.4 cm−1 was achieved when the modulation depth was set to the optimum value of 0.188 cm−1. The ppb-level detection sensitivity verified the design of the reported QEPAS method and makes it suitable for use in environmental monitoring and other applications.Item Quartz-tuning-fork enhanced photothermal spectroscopy for ultra-high sensitive trace gas detection(Optical Society of America, 2018) Ma, Yufei; He, Ying; Tong, Yao; Yu, Xin; Tittel, Frank K.A gas sensing method based on quartz-tuning-fork enhanced photothermal spectroscopy (QEPTS) is reported in this paper. Unlike usually used thermally sensitive elements, a sharply resonant quartz-tuning-fork with the capability of enhanced mechanical resonance was used to amplify the photothermal signal level. Acetylene (C2H2) detection was used to verify the QEPTS sensor performance. The measured results indicate a minimum detection limit (MDL) of 718 ppb and a normalized noise equivalent absorption coefficient (NNEA) of 7.63 × 10−9 cm−1W/√Hz. This performance demonstrates that QEPTS can be an ultra-high sensitive technique for gas detection and shows superiority when compared to usually used methods of tunable diode laser absorption spectroscopy (TDLAS) and quartz-enhanced photoacoustic spectroscopy (QEPAS). Furthermore, when compared to an optical detector, especially a costly mercury cadmium telluride (MCT) detector with cryogenic cooling used in TDLAS, a quartz-tuning-fork is much cheap and tiny. Besides, compared to the QEPAS technique, QEPTS is a non-contact measurement technique and therefore can be used for standoff and remote trace gas detection.