Browsing by Author "Said, Ibrahim A."

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    Modeling and experimental validation of nanophotonics-enhanced solar membrane distillation technology for treating reverse osmosis brine
    (Springer Nature, 2024) Elrakhawi, Mayar; Tayel, Ahmed F.; Abdelrazek, Amr; He, Ze; Li, Qilin; Said, Ibrahim A.; Nanosystems Engineering Research Center for Nanotechnology-Enabled Water Treatment (NEWT)
    A novel, cost-efficient Nanophotonic Enhanced Solar Membrane Distillation (NESMD) system, a solar-driven water desalination technology, was studied. The system features a photothermal membrane acting as a solar collector for water distillation, thus eliminating the need for an external condenser. To address the system’s vulnerability to thermal losses, a comprehensive mathematical model was developed and validated against real-world experimental data. This model represents intricately coupled heat and mass transfer within a sweeping-air NESMD system, incorporating heat loss considerations. The modeling strategy involved dividing the NESMD module into sub-cells and implementing a finite difference method for detailed analysis. This led to a series of nonlinear simultaneous equations, which were resolved via computational code using MATLAB software. The developed NESMD model exhibited commendable conformity to experimental data, exhibiting a relative percentage error of less than 10% for average permeate flux and identifying thermal losses as high as 63%. Depending on the operating conditions, heat transferred to the surroundings takes the lead among the heat loss contributors at higher feed rates (up to 25%), whereas heat conduction across the membrane dominates (up to 42%) thermal losses at low feed rates. The study established an exponential correlation between permeate production and solar energy, with a heat transfer coefficient ranging from 9.5 to 30 W m−2 K−1 and a coefficient of determination of 0.96. An integral part of this work includes calculating solar energy utilization and clarifying the system’s performance. Furthermore, this study examines the influence of diverse operational and geometric parameters, providing insights into enhancing production rates. Hence, an increase in feed layer thickness enhances freshwater production by 7%. Due to the intensification of solar irradiance, freshwater production increased ninefold, and specific energy consumption decreased by 134 kW hr m−3. This research underscores the potential of NESMD for sustainable desalination, providing a validated model that lays the groundwork for future advancements in membrane distillation technology.
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    Room-Temperature Catalytic Treatment of High-Salinity Produced Water at Neutral pH
    (American Chemical Society, 2020) Yin, Y. Ben; Coonrod, Christian L.; Heck, Kimberly N.; Said, Ibrahim A.; Powell, Camilah D.; Guo, Sujin; Reynolds, Michael A.; Wong, Michael S.
    Produced waters from hydraulic fracturing (HFPW) operations greatly challenge traditional water treatment technologies due to the high concentrations of total dissolved solids (TDS), highly complex and variable water matrices, and significant residual hydrocarbon content. We recently reported the unusual ability of a PdAu catalyst to degrade phenol in simulated HFPW at room temperature by generating H2O2 in situ from formic acid and air. Phenol removal occurred at TDS levels as high as ∼10 000 ppm (ionic strength I = 0.3 M), but the catalytic reaction required pH < 4 to proceed. Here, we find that PdAu, Pd, and Au degraded phenol in the pH 5–8 range by using hydroxylamine as the hydrogen source in place of formic acid. Pd exhibited the highest activity, and Au the least. Activity of the monometallic catalysts decreased >70% as TDS increased from 0 to ∼100 000 ppm (I = 3 M), whereas the PdAu was comparatively less affected (∼50% activity decrease). All catalysts remained active at TDS levels as high as 100 000 ppm. The majority of the hydroxylamine formed N2, however this reaction generated additional nitrite/nitrate anion byproducts with nitrogen selectivities ranging from 0.5% to 11.5%, depending on the catalyst identity and reaction salinity. To demonstrate one possible flow treatment process concept, we constructed and tested a recirculating trickle bed reactor that removed 28% phenol from simulated HFPW over 48 h. These results show the potential of oxidation catalysis as a treatment approach for produced water and other high-salinity industrial wastewaters.
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    Selective membranes in water and wastewater treatment: Role of advanced materials
    (Elsevier, 2021) Zuo, Kuichang; Wang, Kunpeng; DuChanois, Ryan M.; Fang, Qiyi; Deemer, Eva M.; Huang, Xiaochuan; Xin, Ruikun; Said, Ibrahim A.; He, Ze; Feng, Yuren; Walker, W. Shane; Lou, Jun; Elimelech, Menachem; Huang, Xia; Li, Qilin; NSF Nanosystems Engineering Research Center for Nanotechnology-Enabled Water Treatment
    Membrane separation has enjoyed tremendous advances in relevant material and engineering sciences, making it the fastest growing technology in water treatment. Although membranes as a broad-spectrum physical barrier have great advantages over conventional treatment processes in a myriad of applications, the need for higher selectivity and specificity in membrane separation is rising as we move to target contaminants at trace concentrations and to recover valuable chemicals from wastewater with low energy consumption. In this review, we discuss the drivers, fundamental science, and potential enabling materials for high selectivity membranes, as well as their applications in different water treatment processes. Membrane materials and processes that show promise to achieve high selectivity for water, ions, and small molecules—as well as the mechanisms involved—are highlighted. We further identify practical needs, knowledge gaps, and technological barriers in both material development and process design for high selectivity membrane processes. Finally, we discuss research priorities in the context of existing and future water supply paradigms.