Browsing by Author "Lamb, Michael P."
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Item Arctic Permafrost Thawing Enhances Sulfide Oxidation(Wiley, 2023) Kemeny, Preston Cosslett; Li, Gen K.; Douglas, Madison; Berelson, William; Chadwick, Austin J.; Dalleska, Nathan F.; Lamb, Michael P.; Larsen, William; Magyar, John S.; Rollins, Nick E.; Rowland, Joel; Smith, M. Isabel; Torres, Mark A.; Webb, Samuel M.; Fischer, Woodward W.; West, A. JoshuaPermafrost degradation is altering biogeochemical processes throughout the Arctic. Thaw-induced changes in organic matter transformations and mineral weathering reactions are impacting fluxes of inorganic carbon (IC) and alkalinity (ALK) in Arctic rivers. However, the net impact of these changing fluxes on the concentration of carbon dioxide in the atmosphere (pCO2) is relatively unconstrained. Resolving this uncertainty is important as thaw-driven changes in the fluxes of IC and ALK could produce feedbacks in the global carbon cycle. Enhanced production of sulfuric acid through sulfide oxidation is particularly poorly quantified despite its potential to remove ALK from the ocean-atmosphere system and increase pCO2, producing a positive feedback leading to more warming and permafrost degradation. In this work, we quantified weathering in the Koyukuk River, a major tributary of the Yukon River draining discontinuous permafrost in central Alaska, based on water and sediment samples collected near the village of Huslia in summer 2018. Using measurements of major ion abundances and sulfate (SO42− {\textSO_4^2-\) sulfur (34S/32S) and oxygen (18O/16O) isotope ratios, we employed the MEANDIR inversion model to quantify the relative importance of a suite of weathering processes and their net impact on pCO2. Calculations found that approximately 80% of SO42− {\textSO_4^2-\ in mainstem samples derived from sulfide oxidation with the remainder from evaporite dissolution. Moreover, 34S/32S ratios, 13C/12C ratios of dissolved IC, and sulfur X-ray absorption spectra of mainstem, secondary channel, and floodplain pore fluid and sediment samples revealed modest degrees of microbial sulfate reduction within the floodplain. Weathering fluxes of ALK and IC result in lower values of pCO2 over timescales shorter than carbonate compensation (∼104 yr) and, for mainstem samples, higher values of pCO2 over timescales longer than carbonate compensation but shorter than the residence time of marine SO42− {\textSO_4^2-\ (∼107 yr). Furthermore, the absolute concentrations of SO42− {\textSO_4^2-\ and Mg2+ in the Koyukuk River, as well as the ratios of SO42− {\textSO_4^2-\ and Mg2+ to other dissolved weathering products, have increased over the past 50 years. Through analogy to similar trends in the Yukon River, we interpret these changes as reflecting enhanced sulfide oxidation due to ongoing exposure of previously frozen sediment and changes in the contributions of shallow and deep flow paths to the active channel. Overall, these findings confirm that sulfide oxidation is a substantial outcome of permafrost degradation and that the sulfur cycle responds to permafrost thaw with a timescale-dependent feedback on warming.Item Burial and Exhumation of Sedimentary Rocks Revealed by the Base Stimson Erosional Unconformity, Gale Crater, Mars(Wiley, 2022) Watkins, Jessica A.; Grotzinger, John P.; Stein, Nathan T.; Banham, Steven G.; Gupta, Sanjeev; Rubin, David M.; Morgan, Kathryn Stack; Edgett, Kenneth S.; Frydenvang, Jens; Siebach, Kirsten L.; Lamb, Michael P.; Sumner, Dawn Y.; Lewis, Kevin W.Sedimentary rocks record the ancient climate of Mars through changes between subaqueous and eolian depositional environments, recognized by their stratal geometries and suites of sedimentary structures. Orbiter- and rover-image-based geologic mapping show a dynamic evolution of the 5-km-thick sedimentary sequence exposed along the flanks of Aeolis Mons (informally, Mt. Sharp) in Gale crater, Mars, by deposition of subaqueous strata followed by exhumation via eolian erosion and then deposition of overlying, onlapping strata of inferred eolian origin. This interpretation suggests that a significant unconformity should occur at the base of the onlapping strata, thus predicting lateral variations in elevation along the contact between the underlying Mt. Sharp group and overlying Stimson formation. Curiosity rover and high-resolution orbital image data quantify paleotopographic variability associated with the contact; ∼140 m of net elevation change and a slope closely aligned with the modern topography is expressed along the regional contact. These results support the interpretation of an erosional unconformity between these strata and that it was likely formed as a result of eolian erosion within the crater, indicative of a transition from wet to dry climate and providing insight into the stratigraphic context, geologic history, and habitability within Gale crater.Item Testing morphodynamic controls on the location and frequency of river avulsions on fans versus deltas: Huanghe (Yellow River), China(American Geophysical Union, 2014) Ganti, Vamsi; Chu, Zhongxin; Lamb, Michael P.; Nittrouer, Jeffrey A.; Parker, GaryA mechanistic understanding of river avulsion location and frequency is needed to predict the growth of alluvial fans and deltas. The Huanghe, China, provides a rare opportunity to test emerging theories because its high sediment load produces regular avulsions at two distinct nodes. Where the river debouches from the Loess Plateau, avulsions occur at an abrupt decrease in bed slope and reoccur at a time interval (607 years) consistent with a channel-filling timescale set by the superelevation height of the levees. Downstream, natural deltaic avulsions reoccur at a timescale that is fast (7 years) compared to channel-filling timescale due to large stage-height variability during floods. Unlike the upstream node, deltaic avulsions cluster at a location influenced by backwater hydrodynamics and show evidence for episodic downstream migration in concert with progradation of the shoreline, providing new expectations for the interplay between avulsion location, frequency, shoreline rugosity, and delta morphology.