Browsing by Author "Guo, Ting"
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Item Array of fullerene nanotubes(2009-12-15) Smalley, Richard E.; Colbert, Daniel T.; Dai, Hongjie; Liu, Jie; Rinzler, Andrew G.; Hafner, Jason H.; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThis invention relates generally to forming an array of fullerene nanotubes. In one embodiment, a macroscopic molecular array is provided comprising at least about 106 fullerene nanotubes in generally parallel orientation and having substantially similar lengths in the range of from about 5 to about 500 nanometers.Item Array of single-wall carbon nanotubes(2006-07-04) Smalley, Richard E.; Colbert, Daniel T.; Dai, Hongjie; Liu, Jie; Rinzler, Andrew G.; Hafner, Jason H.; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThis invention relates generally to forming an array of single-wall carbon nanotubes (SWNT). In one embodiment, a macroscopic molecular array is provided comprising at least about 106 single-wall carbon nanotubes in generally parallel orientation and having substantially similar lengths in the range of from about 5 to about 500 nanometers.Item Carbon fibers formed from single-wall carbon nanotubes(2004-01-27) Smalley, Richard E.; Colbert, Daniel T.; Dai, Hongjie; Liu, Jie; Rinzler, Andrew G.; Hafner, Jason H.; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeA method for purifying a mixture comprising single-wall carbon nanotubes and amorphous carbon contaminate is disclosed. The method includes the steps of heating the mixture under oxidizing conditions sufficient to remove the amorphous carbon, followed by recovering a product comprising at least about 80% by weight of single-wall carbon nanotubes. A method for producing tubular carbon molecules of about 5 to 500 nm in length is also disclosed. The method includes the steps of cutting single-wall nanotube containing-material to form a mixture of tubular carbon molecules having lengths in the range of 5-500 nm and isolating a fraction of the molecules having substantially equal lengths. The nanotubes may be used, singularly or in multiples, in power transmission cables, in solar cells, in batteries, as antennas, as molecular electronics, as probes and manipulators, and in composites.Item Continuous fiber of fullerene nanotubes(2010-02-02) Smalley, Richard E.; Colbert, Daniel T.; Dai, Hongjie; Liu, Jie; Rinzler, Andrew G.; Hafner, Jason H.; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThis invention relates generally to carbon fiber produced from fullerene nanotube arrays. In one embodiment, the present invention involves a macroscopic carbon fiber comprising at least 106 fullerene nanotubes in generally parallel orientation.Item Continuous fiber of single-wall carbon nanotubes(2005-12-27) Smalley, Richard E.; Colbert, Daniel T.; Dai, Hongjie; Liu, Jie; Rinzler, Andrew G.; Hafner, Jason H.; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThis invention relates generally to carbon fiber produced from single-wall carbon nanotube (SWNT) molecular arrays. In one embodiment, the present invention involves a macroscopic carbon fiber comprising at least 106 signal-wall carbon nanotubes in generally parallel orientation.Item Electrical conductors comprising single-wall carbon nanotubes(2005-11-29) Smalley, Richard E.; Colbert, Daniel T.; Guo, Ting; Rinzler, Andrew G.; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThe present invention concerns electrical conductors comprising armchair single-wall carbon nanotubes. Such electrical conductors made by the invention are metallic, i.e., they will conduct electrical charges with a relatively low resistance. The amount of armchair single-wall carbon nanotubes in the electrical conductor can be greater than 10%, greater than 30%, greater than 50%, greater than 75%, and greater than 90%, of the single-wall carbon nanotubes in the electrical conductor.Item Fullerene nanotube compositions(2008-06-24) Smalley, Richard E.; Colbert, Daniel T.; Dai, Hongjie; Liu, Jie; Rinzler, Andrew G.; Hafner, Jason H.; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThis invention relates generally to a fullerene nanotube composition. The fullerene nanotubes may be in the form of a felt, such as a bucky paper. Optionally, the fullerene nanotubes may be derivatized with one or more functional groups. Devices employing the fullerene nanotubes of this invention are also disclosed.Item Macroscopically manipulable nanoscale devices made from nanotube assemblies(2006-05-23) Colbert, Daniel T.; Dai, Hongjie; Hafner, Jason H.; Rinzler, Andrew G.; Smalley, Richard E.; Liu, Jie; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeMacroscopically manipulable nanoscale devices made from nanotube assemblies are disclosed. The article of manufacture comprises a macroscopic mounting element capable of being manipulated or observed in a macroscale environment, and a nanoscale nanotube assembly attached to the mounting element. The article permits macroscale information to be provided to or obtained from a nanoscale environment. A method for making a macroscopically manipulable nanoscale devices comprises the steps of (1) providing a nanotube-containing material; (2) preparing a nanotube assembly device having at least one carbon nanotube for attachment; and (3) attaching said nanotube assembly to a surface of a mounting element.Item Macroscopically manipulable nanoscale devices made from nanotube assemblies(2011-06-14) Colbert, Daniel T.; Dai, Hongjie; Hafner, Jason H.; Rinzler, Andrew G.; Smalley, Richard E.; Liu, Jie; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThis invention relates generally to cutting single-wall carbon nanotubes (SWNT). In one embodiment, the present invention provides for preparations of homogeneous populations of short carbon nanotube molecules by cutting and annealing (reclosing) the nanotube pieces followed by fractionation. The cutting and annealing processes may be carried out on a purified nanotube bucky paper, on felts prior to purification of nanotubes or on any material that contains single-wall nanotubes. In one embodiment, oxidative etching with concentrated nitric acid is employed to cut SWNTs into shorter lengths. The annealed nanotubes may be disbursed in an aqueous detergent solution or an organic solvent for the fractionation. Closed tubes can also be derivatized to facilitate fractionation, for example, by adding solubilizing moieties to the end caps.Item Membrane comprising an array of single-wall carbon nanotubes(2007-04-17) Smalley, Richard E.; Colbert, Daniel T.; Dai, Hongjie; Liu, Jie; Rinzler, Andrew G.; Hafner, Jason H.; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThis invention relates generally to membranes comprising an array of single-wall carbon nanotubes (SWNT) wherein the membrane is nanoporous. In one embodiment, the membrane comprises a substantially two-dimensional array of a homogeneous population of single-walled nanotubes aggregated in substantially parallel orientation to form a monolayer extending in directions substantially perpendicular to the orientation of the individual nanotubes. Using single-wall carbon nanotubes of the same type and structure provides a homogeneous array. By using different single-wall carbon nanotubes, either a random or ordered heterogeneous structure can be produced by employing successive reactions after removal of previously masked areas of a substrate. Other embodiments of the invention include batteries comprising a membrane comprising an array of single-wall carbon nanotubes or carbon fibers that are aggregates of single-wall carbon nanotubes, and wherein the plurality of single-wall carbon nanotubes are in a generally parallel orientation.Item Method for cutting fullerene nanotubes(2009-01-27) Smalley, Richard E.; Colbert, Daniel T.; Dai, Hongjie; Liu, Jie; Rinzler, Andrew G.; Hafner, Jason H.; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThis invention relates generally to cutting fullerene nanotubes. In one embodiment, the present invention provides for preparation of homogeneous populations of short fullerene nanotubes by cutting and annealing (reclosing) the nanotube pieces followed by fractionation. The cutting and annealing processes may be carried out on a purified nanotube bucky paper, on felts prior to purification of nanotubes or on any material that contains fullerene nanotubes. In one embodiment, oxidative etching with concentrated nitric acid is employed to cut fullerene nanotubes into shorter lengths. The annealed nanotubes may be disbursed in an aqueous detergent solution or an organic solvent for the fractionation. Closed tubes can also be derivatized to facilitate fractionation, for example, by adding solubilizing moieties to the end caps.Item Method for cutting nanotubes(2006-03-07) Smalley, Richard E.; Colbert, Daniel T.; Dai, Hongjie; Liu, Jie; Rinzler, Andrew G.; Hafner, Jason H.; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThis invention relates generally to cutting single-wall carbon nanotubes (SWNT). In one embodiment, the present invention provides for preparation of homogeneous populations of short carbon nanotube molecules by cutting and annealing (reclosing) the nanotube pieces followed by fractionation. The cutting and annealing processes may be carried out on a purified nanotube bucky paper, on felts prior to purification of nanotubes or on any material that contains single-wall nanotubes. In one embodiment, oxidative etching with concentrated nitric acid is employed to cut SWNTs into shorter lengths. The annealed nanotubes may be disbursed in an aqueous detergent solution or an organic solvent for the fractionation. Closed tubes can also be derivatized to facilitate fractionation, for example, by adding solubilizing moieties to the end caps.Item Method for cutting single-wall carbon nanotubes(2006-05-30) Colbert, Daniel T.; Dai, Hongjie; Hafner, Jason H.; Rinzler, Andrew G.; Smalley, Richard E.; Liu, Jie; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThis invention relates generally to cutting single-wall carbon nanotubes (SWNT). In one embodiment, the present invention provides for preparations of homogemeous populations of short carbon nanotube molecules by cutting and annealing (reclosing) the nanotube pieces followed by fractionation. The cutting and annealing processes may be carried out on a purified nanotube bucky paper, on felts prior to purification of nanotubes or on any material that contains single-wall nanotubes. In one embodiment, oxidative etching with concentrated nitric acid is employed to cut SWNTs into shorter lengths. The annealed nanotubes may be disbursed in an aqueous detergent solution or an organic solvent for the fractionation. Closed tubes can also be derivatized to facilitate fractionation, for example, by adding solubilizing moieties to the end caps.Item Method for forming a patterned array of fullerene nanotubes(2009-03-31) Smalley, Richard E.; Colbert, Daniel T.; Dai, Hongjie; Liu, Jie; Rinzler, Andrew G.; Hafner, Jason H.; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThis invention relates generally to forming a patterned array of fullerene nanotubes. In one embodiment, a nanoscale array of microwells is provided on a substrate; a metal catalyst is deposited in each microwells; and a stream of hydrocarbon or CO feedstock gas is directed at the substrate under conditions that effect growth of fullerene nanotubes from each microwell.Item Method for forming a patterned array of single-wall carbon nanotubes(2006-09-19) Smalley, Richard E.; Colbert, Daniel T.; Dai, Hongjie; Liu, Jie; Rinzler, Andrew G.; Hafner, Jason H.; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThis invention relates generally to forming a patterned array of single-wall carbon nanotubes (SWNT). In one embodiment, a nanoscale array of microwells is provided on a substrate; a metal catalyst is deposited in each microwells; and a stream of hydrocarbon or CO feedstock gas is directed at the substrate under conditions that effect growth of single-wall carbon nanotubes from each microwell.Item Method for forming an array of single-wall carbon nanotubes in an electric field and compositions thereof(2006-08-08) Smalley, Richard E.; Colbert, Daniel T.; Dai, Hongjie; Liu, Jie; Rinzler, Andrew G.; Hafner, Jason H.; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThis invention relates generally to a forming an array of single-wall carbon nanotubes (SWNT) in an electric field and compositions thereof. In one embodiment, a purified bucky paper of single-wall carbon nanotubes is used as the starting material. Upon oxidative treatment of the bucky paper surface, many tube and/or rope ends protrude up from the surface of the paper. Disposing the resulting bucky paper in an electric field results in the protruding tubes and or ropes of single-wall carbon nanotubes aligning in a direction substantially perpendicular to the paper surface. These tubes tend to coalesce to form a molecular array. In another embodiment, a molecular array of SWNTs can be made by “combing” the purified bucky paper starting material with a sharp microscopic tip to align the nanotubes.Item Method for forming composites of sub-arrays of fullerene nanotubes(2011-05-10) Smalley, Richard E.; Colbert, Daniel T.; Dai, Hongjie; Liu, Jie; Rinzler, Andrew G.; Hafner, Jason H.; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThe formation of arrays of fullerene nanotubes is described. A microscopic molecular array of fullerene nanotubes is formed by assembling subarrays of up to 106 fullerene nanotubes into a composite array.Item Method for forming composites of sub-arrays of single-wall carbon nanotubes(2006-01-17) Smalley, Richard E.; Colbert, Daniel T.; Dai, Hongjie; Liu, Jie; Rinzler, Andrew G.; Hafner, Jason H.; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThis invention relates generally to forming arrays of single-wall carbon nanotubes (SWNT). In one embodiment, the present invention involves forming a macroscopic molecular array of tubular carbon molecules, said method comprising the step of assembling subarrays of up to 106 single-wall carbon nanotubes into a composite array.Item Method for fractionating single-wall carbon nanotubes(2008-04-15) Colbert, Daniel T.; Dai, Hongjie; Hafner, Jason H.; Rinzler, Andrew G.; Smalley, Richard E.; Liu, Jie; Smith, Kenneth A.; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThe invention relates generally to dispersing and fractionating single-wall carbon nanotubes, which can be derivatized to facilitate fractionation, for example, by adding solubilizing moieties to the nanotubes.Item Method for growing continuous carbon fiber and compositions thereof(2004-06-29) Colbert, Daniel T.; Dai, Hongjie; Hafner, Jason H.; Rinzler, Andrew G.; Smalley, Richard E.; Smith, Kenneth A.; Liu, Jie; Guo, Ting; Nikolaev, Pavel; Thess, Andreas; Rice University; United States Patent and Trademark OfficeThis invention relates generally to a method for growing carbon fiber from single-wall carbon nanotube (SWNT) molecular arrays. The carbon fiber which comprises an aggregation of substantially parallel carbon nanotubes may be produced by growth (elongation) of a suitable seed molecular array. The first step is to open the growth end of the SWNTs in the molecular array. Next, a transition metal catalyst is added to the open-ended seed array. In the next step, the SWNT molecular array with catalyst deposited on the open tube ends is subjected to tube growth (extension) conditions. The carbon supply necessary to grow the SWNT molecular array into a continuous fiber is supplied to the SWNT molecular array tip heated to a temperature sufficient to cause growth to any desired length. The continuous carbon fiber can also be grown from more than one separately prepared molecular arrays or templates.