Zhou, ZheMa, ZhiweiBehnke, Nicole ErinGao, HongyinKürti, László2017-01-272017-01-272017Zhou, Zhe, Ma, Zhiwei, Behnke, Nicole Erin, et al.. "Non-Deprotonative Primary and Secondary Amination of (Hetero)Arylmetals." <i>Journal of the American Chemical Society,</i> 139, no. 1 (2017) American Chemical Society: 115-118. http://dx.doi.org/10.1021/jacs.6b12712.https://hdl.handle.net/1911/93785Herein we disclose a novel method for the facile transfer of primary (−NH2) and secondary amino groups (−NHR) to heteroaryl- as well as arylcuprates at low temperature without the need for precious metal catalysts, ligands, excess reagents, protecting and/or directing groups. This one-pot transformation allows unprecedented functional group tolerance and it is well-suited for the amination of electron-rich, electron-deficient as well as structurally complex (hetero)arylmetals. In some of the cases, only catalytic amounts of a copper(I) salt is required.engThis is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by the American Chemical Society.Journal articlehttp://dx.doi.org/10.1021/jacs.6b12712