Swearer, Dayne F.Gottheim, SamuelSimmons, Jay G.Phillips, Dane J.Kale, Matthew J.McClain, Michael J.Christopher, PhillipHalas, Naomi J.Everitt, Henry O.2018-11-092018-11-092018Swearer, Dayne F., Gottheim, Samuel, Simmons, Jay G., et al.. "Monitoring Chemical Reactions with Terahertz Rotational Spectroscopy." <i>ACS Photonics,</i> 5, no. 8 (2018) American Chemical Society: 3097-3106. https://doi.org/10.1021/acsphotonics.8b00342.https://hdl.handle.net/1911/103293Rotational spectroscopy is introduced as a new in situ method for monitoring gas-phase reactants and products during chemical reactions. Exploiting its unambiguous molecular recognition specificity and extraordinary detection sensitivity, rotational spectroscopy at terahertz frequencies was used to monitor the decomposition of carbonyl sulfide (OCS) over an aluminum nanocrystal (AlNC) plasmonic photocatalyst. The intrinsic surface oxide on AlNCs is discovered to have a large number of strongly basic sites that are effective for mediating OCS decomposition. Spectroscopic monitoring revealed two different photothermal decomposition pathways for OCS, depending on the absence or presence of H2O. The strength of rotational spectroscopy is witnessed through its ability to detect and distinguish isotopologues of the same mass from an unlabeled OCS precursor at concentrations of <1 nanomolar or partial pressures of <10 μTorr. These attributes recommend rotational spectroscopy as a compelling alternative for monitoring gas-phase chemical reactants and products in real time.engThis is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.Journal articlealuminum nanocrystalscarbonyl sulfidephotocatalysisplasmonicsrotational spectroscopyChemicalReactionshttps://doi.org/10.1021/acsphotonics.8b00342