Margrave, John L.2018-12-182018-12-181977Hamill, Delphia F.. "Matrix reactions of uranium fluorides as studied by infrared spectroscopy." (1977) Master’s Thesis, Rice University. <a href="https://hdl.handle.net/1911/104755">https://hdl.handle.net/1911/104755</a>.https://hdl.handle.net/1911/104755The Infrared spectra of UF^4 were recorded In matrices of neon, argon, krypton, xenon, oxygen, nitrogen, nitric oxide, and carbon monoxide* The data from these spectra support a tetrahedral structure for UF^4 in the gas phase. The relative interaction of the above-mentioned matrices with UF^4. was found to increase in order from neon 4 to carbon monoxide. The deposition of UF^4 in fluorine doped argon and nitrogen matrices resulted in production of UF^5 and UF^6, the relative intensities of their respective infrared bands depending on the concentration of fluorine in the matrix. Nitrogen and carbon monoxide doped argon matrices were also studied.91 ppengCopyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder.ThesisRICE2391reformatted digitalThesis Chem. 1977 Hamill