Nicolaou, K.C.Shah, Akshay A.Korman, HenryKhan, TabrezShi, LeiWorawalai, WisuttayaTheodorakis, Emmanuel A.2016-10-212016-10-212015Nicolaou, K.C., Shah, Akshay A., Korman, Henry, et al.. "Total Synthesis and Structural Revision of Antibiotic CJ-16,264." <i>Angewandte Chemie,</i> 54, no. 32 (2015) Wiley: 9203-9208. http://dx.doi.org/10.1002/anie.201504337.https://hdl.handle.net/1911/91977The total synthesis and structural revision of antibiotic CJ-16,264 is described. Starting with citronellal, the quest for the target molecule featured a novel bis-transannular Diels-Alder reaction that casted stereoselectively the decalin system and included the synthesis of six isomers before demystification of its true structure.engThis is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by Wiley.Journal articleantibioticnatural productsstructural revisiontotal synthesistransannular Diels-Alder reactionhttp://dx.doi.org/10.1002/anie.201504337