Matrix reactions of uranium fluorides as studied by infrared spectroscopy

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dc.contributor.advisorMargrave, John L.
dc.creatorHamill, Delphia F.
dc.date.accessioned2018-12-18T21:30:20Z
dc.date.available2018-12-18T21:30:20Z
dc.date.issued1977
dc.description.abstractThe Infrared spectra of UF^4 were recorded In matrices of neon, argon, krypton, xenon, oxygen, nitrogen, nitric oxide, and carbon monoxide* The data from these spectra support a tetrahedral structure for UF^4 in the gas phase. The relative interaction of the above-mentioned matrices with UF^4. was found to increase in order from neon 4 to carbon monoxide. The deposition of UF^4 in fluorine doped argon and nitrogen matrices resulted in production of UF^5 and UF^6, the relative intensities of their respective infrared bands depending on the concentration of fluorine in the matrix. Nitrogen and carbon monoxide doped argon matrices were also studied.
dc.format.digitalOriginreformatted digital
dc.format.extent91 pp
dc.identifier.callnoThesis Chem. 1977 Hamill
dc.identifier.citationHamill, Delphia F.. "Matrix reactions of uranium fluorides as studied by infrared spectroscopy." (1977) Master’s Thesis, Rice University. <a href="https://hdl.handle.net/1911/104755">https://hdl.handle.net/1911/104755</a>.
dc.identifier.digitalRICE2391
dc.identifier.urihttps://hdl.handle.net/1911/104755
dc.language.isoeng
dc.rightsCopyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder.
dc.titleMatrix reactions of uranium fluorides as studied by infrared spectroscopy
dc.typeThesis
dc.type.materialText
thesis.degree.departmentChemistry
thesis.degree.disciplineNatural Sciences
thesis.degree.grantorRice University
thesis.degree.levelMasters
thesis.degree.nameMaster of Arts
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